{"id":"W2134566996","doi":"10.1002/chin.201117061","title":"ChemInform Abstract: Iridium as a General Catalyst for the Decarbonylative Addition of Aldehydes to Alkynes.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Iridium; Catalysis; Decarbonylation; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002184192,0.0007094144,0.0001794845,0.0004690029,0.000287298,0.0003783873,0.0005728654,0.0003973851,0.007492709],"category_scores_gemma":[0.000182211,0.0002540307,0.0001278285,0.0003807146,0.00025997,0.0004855304,0.000486238,0.0006624272,0.002266045],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006201584,"about_ca_system_score_gemma":0.0004519532,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001010947,"about_ca_topic_score_gemma":0.001483772,"domain_scores_codex":[0.999824,0.00002199688,0.000009356986,0.00004691571,0.00006509198,0.00003262547],"domain_scores_gemma":[0.9999654,0.000005024495,0.000008806304,0.000006109351,0.000007117152,0.000007404677],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008593577,0.0001414961,0.0004520734,0.001341022,0.00005095307,0.0004634205,0.00009877294,0.001112802,0.8908581,0.01121255,0.01854041,0.07486898],"study_design_scores_gemma":[0.0001136702,0.0002372302,0.0004934132,0.00004027318,0.00004528014,0.0003843792,0.00001641736,0.0009855438,0.9567104,0.0003002925,0.04065669,0.00001642389],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5548005,0.02058215,0.05143461,0.002401817,0.001454666,0.0005107847,0.003593547,0.003565971,0.3616559],"genre_scores_gemma":[0.9507206,0.006089275,0.008971973,0.0002118014,0.0001548547,0.00007292277,0.001556694,0.0001995014,0.03202235],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007492709,"threshold_uncertainty_score":0.02506566,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02364807725126087,"score_gpt":0.2511552433997261,"score_spread":0.2275071661484653,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}