{"id":"W2134708455","doi":"10.1021/ma049797v","title":"NMR Studies of PAH/PSS Polyelectrolyte Multilayers Adsorbed onto Silica","year":2004,"lang":"en","type":"article","venue":"Macromolecules","topic":"Polymer Surface Interaction Studies","field":"Materials Science","cited_by":74,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Polyelectrolyte; Allylamine; Polyelectrolyte adsorption; Sulfonate; Chemistry; Chemical engineering; Adsorption; Layer by layer; Styrene; Polymer chemistry; NMR spectra database; Nuclear magnetic resonance spectroscopy; Colloid; Polymer; Layer (electronics); Sodium; Copolymer; Organic chemistry; Spectral line","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001599228,0.0003925025,0.0001871302,0.0001886897,0.0002141285,0.0001703337,0.0001384579,0.0002131052,0.0006354155],"category_scores_gemma":[0.0002408621,0.0001756806,0.000184216,0.0001279647,0.000159778,0.0002404564,0.0001530559,0.000352199,0.0002461927],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002312697,"about_ca_system_score_gemma":0.000101811,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007450507,"about_ca_topic_score_gemma":0.0009055557,"domain_scores_codex":[0.9998864,0.00001344226,0.000007044306,0.00001894502,0.00004631183,0.00002780182],"domain_scores_gemma":[0.9998216,0.00004809472,0.00003841832,0.00001292397,0.0000392799,0.0000397131],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00001515079,0.000003876141,0.00004389461,0.00001109292,0.000002356403,0.00000989513,0.0000104546,0.00003312265,0.9997026,0.00000739607,0.000004638222,0.0001554222],"study_design_scores_gemma":[0.000005513242,0.0001508316,0.002711639,0.000005621638,0.00001392837,0.00004537126,0.0000260592,0.001142821,0.9954734,0.00001337038,0.0004070985,0.000004482354],"study_design_candidate":"observational","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972755,0.0004742396,0.001463851,0.00002949341,0.00001180647,0.000008215118,0.00007041592,0.00003867149,0.0006277545],"genre_scores_gemma":[0.9949051,0.000554852,0.002751617,0.00004095631,0.0000152485,0.00001354982,0.0001809531,0.00001894652,0.001518703],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007450507,"threshold_uncertainty_score":0.00212568,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02640578388580069,"score_gpt":0.312249840554754,"score_spread":0.2858440566689534,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}