{"id":"W2135239044","doi":"10.1002/anie.200700560","title":"α‐Amino Acid Induced Rate Acceleration in Aqueous Biphasic Lewis Acid Catalyzed Michael Addition Reactions","year":2007,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Catalysis; Aqueous solution; Alanine; Chemistry; Environmentally friendly; Lewis acids and bases; Amino acid; Michael reaction; Organic chemistry; Aqueous two-phase system; Metal; Polymer chemistry; Biochemistry; Biology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003216858,0.0005411322,0.0003151775,0.0002398654,0.000156739,0.0003324565,0.000384161,0.0003206716,0.001802116],"category_scores_gemma":[0.0003602166,0.0002706992,0.000214217,0.0002211453,0.0002092501,0.0004692743,0.0004182164,0.0006111877,0.000993254],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002995984,"about_ca_system_score_gemma":0.0002402657,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005384481,"about_ca_topic_score_gemma":0.0007809845,"domain_scores_codex":[0.9997751,0.00005211729,0.00001655652,0.00003299455,0.00006387859,0.00005932425],"domain_scores_gemma":[0.9998348,0.00004038457,0.00003740009,0.00001498526,0.000037832,0.00003457927],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001046915,0.00002274664,0.00005351973,0.00007824451,0.000005878073,0.00006006227,0.00002565804,0.0001346473,0.995233,0.0004270338,0.0000909785,0.003763573],"study_design_scores_gemma":[0.00001338102,0.00009839282,0.00008972071,0.000003028233,0.000003828497,0.00005253109,0.000005850715,0.0007776589,0.9976678,0.00005862089,0.001224516,0.000004493515],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9507497,0.00306243,0.03436485,0.0003210052,0.0001811162,0.0001473451,0.000225481,0.0005632607,0.01038487],"genre_scores_gemma":[0.9851025,0.001175598,0.007802297,0.0000562543,0.00002518147,0.00003675811,0.0001248339,0.00003446084,0.00564218],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001802116,"threshold_uncertainty_score":0.006028652,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01607629662420375,"score_gpt":0.2676243095751386,"score_spread":0.2515480129509348,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}