{"id":"W2135379428","doi":"10.1039/b606419a","title":"Do zeolite precursor species really exist in aqueous synthesis media?","year":2006,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Zeolite Catalysis and Synthesis","field":"Chemistry","cited_by":63,"is_retracted":false,"has_abstract":true,"ca_institutions":"Lakehead University","funders":"Natural Sciences and Engineering Research Council of Canada; University of Illinois at Urbana-Champaign","keywords":"Silicate; Chemistry; Tetraethyl orthosilicate; Zeolite; Ring (chemistry); Nuclear magnetic resonance spectroscopy; Dodecameric protein; Aqueous solution; Spectroscopy; Orthosilicate; Crystallography; Stereochemistry; Physical chemistry; Organic chemistry; Molecule; Catalysis; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001159515,0.0007084493,0.001038546,0.00002667604,0.00008242177,0.0001396426,0.0008606787,0.0003322655,0.0005717616],"category_scores_gemma":[0.0004488284,0.000700881,0.0006253296,0.0004910232,0.0004679557,0.0002037214,0.0002538858,0.0007262604,0.0001339652],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003686508,"about_ca_system_score_gemma":0.00007995217,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001039514,"about_ca_topic_score_gemma":0.000003432545,"domain_scores_codex":[0.996331,0.00002555683,0.0007247293,0.001137573,0.0008203275,0.0009608502],"domain_scores_gemma":[0.9970692,0.001087788,0.0002713127,0.001144277,0.0001312687,0.0002960921],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007758139,0.001341955,0.0004024738,0.0003950411,0.00005505477,0.00003788102,0.0001815424,0.00004493667,0.9893136,0.001418314,0.001145128,0.005586462],"study_design_scores_gemma":[0.0004063185,0.00000278605,0.0001091859,0.0001640485,0.000109294,0.000008561823,0.00008695792,0.0005882649,0.9732467,0.02185461,0.002632341,0.000790932],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.781356,0.0002005596,0.00001454508,0.0001360743,0.00002211491,0.00006251082,0.0002463768,0.0002016022,0.2177602],"genre_scores_gemma":[0.9943711,0.00002678325,0.0001713539,0.0000334734,0.003317625,0.0001358994,0.0004139715,0.0001113019,0.001418519],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2163417,"threshold_uncertainty_score":0.9995442,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01360327745106782,"score_gpt":0.2236302474838537,"score_spread":0.2100269700327859,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}