{"id":"W2136252185","doi":"10.1002/anie.200802596","title":"Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N‐Heterocyclic Carbene and B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>","year":2008,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":386,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Carbene; Frustrated Lewis pair; Steric effects; Amine gas treating; Chemistry; Boron; Lewis acids and bases; Medicinal chemistry; Hydrogen bond; Crystallography; Stereochemistry; Polymer chemistry; Catalysis; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001237968,0.0005577957,0.0004959263,0.0001530033,0.0001956206,0.00007674927,0.000283772,0.0005750833,0.00009206725],"category_scores_gemma":[0.0002150081,0.0006305422,0.0001620538,0.0002531591,0.000334586,0.0005930048,0.000158341,0.0004950982,0.00001586479],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003349428,"about_ca_system_score_gemma":0.00009708988,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000541388,"about_ca_topic_score_gemma":0.00002727178,"domain_scores_codex":[0.9971808,0.00001976928,0.0007442872,0.0008463975,0.0007564641,0.0004523169],"domain_scores_gemma":[0.9982834,0.0001615227,0.0005376031,0.0003626866,0.0003603783,0.0002943651],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001702646,0.0002990693,0.003121173,0.000221742,0.000245373,0.0000266977,0.0002925447,0.000004464378,0.9869769,0.000003467447,0.006617513,0.002020837],"study_design_scores_gemma":[0.002091617,0.00006084194,0.002705774,0.0002450214,0.00009246916,0.0001711397,0.0001251676,0.0001353392,0.9932944,0.0001033144,0.0003928059,0.0005821018],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971771,0.0003276062,0.00007947522,0.0006876239,0.0002170432,0.0001671681,0.0007229281,0.0001907988,0.0004302942],"genre_scores_gemma":[0.9938986,0.001510453,0.00002074929,0.0002233437,0.001160898,0.00007626606,0.002972555,0.00009205065,0.0000450565],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006317554,"threshold_uncertainty_score":0.9996146,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009962212459527322,"score_gpt":0.2095874186728626,"score_spread":0.1996252062133353,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}