{"id":"W2136252185","doi":"10.1002/anie.200802596","title":"Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N‐Heterocyclic Carbene and B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>","year":2008,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":386,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Carbene; Frustrated Lewis pair; Steric effects; Amine gas treating; Chemistry; Boron; Lewis acids and bases; Medicinal chemistry; Hydrogen bond; Crystallography; Stereochemistry; Polymer chemistry; Catalysis; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001110253,0.0001586718,0.0001384551,0.00006745252,0.0002172395,0.0001704981,0.0003338467,0.0003200556,0.002426601],"category_scores_gemma":[0.0001087318,0.00009736633,0.0001121442,0.00005351051,0.0002246416,0.0002958403,0.0003061815,0.0001863274,0.0003147091],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002408338,"about_ca_system_score_gemma":0.0001640018,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008626106,"about_ca_topic_score_gemma":0.002034011,"domain_scores_codex":[0.9999087,0.000008182075,0.000002861158,0.00001430778,0.00001563887,0.00005039886],"domain_scores_gemma":[0.9999655,0.000006563586,0.000009209508,0.000006401051,0.000002677345,0.000009716295],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006186886,0.00005022718,0.0005210271,0.000100266,0.00002430871,0.0003630081,0.0001117685,0.0007101707,0.9863893,0.004920553,0.0006668062,0.005523736],"study_design_scores_gemma":[0.00007627159,0.0004641832,0.001170591,0.00000510415,0.00001110883,0.0004229617,0.00008029024,0.003026574,0.9905801,0.0004920556,0.003652031,0.00001868378],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9934101,0.0002272334,0.0006616224,0.00005304414,0.00001634991,0.000008338264,0.00004576434,0.00002934073,0.005548222],"genre_scores_gemma":[0.9981924,0.00006226388,0.0003474926,0.00001884837,0.000002769254,0.000004367801,0.00004190761,0.000004624344,0.001325444],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002426601,"threshold_uncertainty_score":0.008117795,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009962212459527322,"score_gpt":0.2095874186728626,"score_spread":0.1996252062133353,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}