{"id":"W2136712276","doi":"10.1139/v06-088","title":"The regioselective α-alkylation of the benzophenone imine of glycinamide, alaninamide, and related derivatives","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Institutes of Health; Eli Lilly and Company","keywords":"Benzophenone; Chemistry; Alkylation; Imine; Schiff base; Regioselectivity; Anhydrous; Medicinal chemistry; Crystal structure; Catalysis; Organic chemistry; Polymer chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001419991,0.00007892773,0.0001470584,0.00001489313,0.00008338183,0.000009656628,0.0001719846,0.00008692139,0.00001377838],"category_scores_gemma":[0.0002538805,0.00004981934,0.0001179875,0.000127559,0.0002645004,0.000003530286,0.00001697578,0.00009310505,4.560885e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000230003,"about_ca_system_score_gemma":0.0002212412,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000518507,"about_ca_topic_score_gemma":0.0008629847,"domain_scores_codex":[0.9993655,0.00002409614,0.0003212378,0.0000842286,0.00009024458,0.0001147018],"domain_scores_gemma":[0.9991167,0.00003774057,0.0004131425,0.0001488809,0.000207088,0.00007648638],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002114264,0.000008330749,0.009268822,0.00001556313,0.00008280616,0.000001443631,0.00003039155,0.00003893702,0.9894579,0.00003170756,0.0004924194,0.0005505162],"study_design_scores_gemma":[0.0002023103,0.0000249344,0.02522631,0.00004455475,0.00004473278,0.00004272331,0.0001277314,0.0000166111,0.9720792,0.0007312092,0.001400934,0.00005880238],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.994872,0.00283253,0.00001840461,0.00044251,0.00001913092,0.00002602388,0.00000948724,4.346327e-7,0.001779487],"genre_scores_gemma":[0.9992056,0.00008152152,0.00003241045,0.000009382165,0.00006796268,5.211739e-7,0.000005693884,0.000006865705,0.0005899736],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01737877,"threshold_uncertainty_score":0.2031574,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002245808087449159,"score_gpt":0.1693085310709803,"score_spread":0.1670627229835312,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}