{"id":"W2136880564","doi":"10.1139/v01-006","title":"Catalytic pathways in the ethanolysis of fenitrothion, an organophosphorothioate pesticide. A dichotomy in the behaviour of crown/cryptand cation complexing agents","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Cryptand; Reactivity (psychology); Nucleophile; Catalysis; Inorganic chemistry; Alkali metal; Medicinal chemistry; Organic chemistry; Ion","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006686173,0.0001772971,0.0003276096,0.0001001962,0.00006034999,0.000041258,0.0008100009,0.0001772466,0.0005106877],"category_scores_gemma":[0.0005182609,0.0001364228,0.000119588,0.0004843478,0.0001331912,0.0001312799,0.00001364882,0.000641038,0.000001071052],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003253287,"about_ca_system_score_gemma":0.000757574,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004981402,"about_ca_topic_score_gemma":0.004416571,"domain_scores_codex":[0.9982284,0.00004610173,0.0007977518,0.0001700744,0.0004532017,0.0003044742],"domain_scores_gemma":[0.9982961,0.0001795563,0.0006159639,0.000434116,0.000235637,0.0002385619],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004560192,0.0001276402,0.03259093,0.0001156647,0.00002308493,0.0003154632,0.00474774,0.00005165012,0.9614542,0.00001871653,0.00009692669,0.0004123416],"study_design_scores_gemma":[0.0007920139,0.00002205943,0.009956105,0.0002759395,0.00007001147,0.0005976812,0.006099523,0.00008036686,0.981074,0.0006802796,0.0001946843,0.0001573433],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997714,0.0001504207,0.00003323607,0.0002463873,0.00003063764,0.00007697992,0.00003371479,0.000002993214,0.001711657],"genre_scores_gemma":[0.9996412,0.00002381696,0.00007247707,0.00009313379,0.00007239839,0.000008116393,0.00003177632,0.00001999572,0.00003710564],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02263483,"threshold_uncertainty_score":0.7530422,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0290180347654638,"score_gpt":0.2489964805376358,"score_spread":0.219978445772172,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}