{"id":"W2137528784","doi":"10.1002/1521-3773(20011203)40:23<4412::aid-anie4412>3.0.co;2-i","title":"Norbornadiene–Quadricyclane Valence Isomerism for a Tetraphosphorus Derivative The Netherlands Organization for Scientific Research (NOW/CW) is acknowledged for partial support (A.L.S., M.L., K.L.), as are the NSERC of Canada for a scholarship (S.B.C.), and EPSRC for funding phosphaorganometallic chemistry at Sussex University (J.F.N.). Dr. H. Zappey is thanked for the HR-MS spectra and J. C. Slootweg for his initiative.","year":2001,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Quadricyclane; Norbornadiene; Ab initio; Valence (chemistry); Phosphorus; Chemistry; Computational chemistry; Derivative (finance); Physical chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts"],"consensus_categories":[],"category_scores_codex":[0.001065929,0.0003111208,0.0003502013,0.00008546508,0.00184816,0.0002480175,0.0006472833,0.0001942161,0.0004987098],"category_scores_gemma":[0.002043888,0.0002426202,0.0002085882,0.0003811439,0.0003531902,0.0003159848,0.0001077629,0.0001432384,4.16286e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005066622,"about_ca_system_score_gemma":0.0004768331,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001635824,"about_ca_topic_score_gemma":0.001286929,"domain_scores_codex":[0.9979078,0.000018498,0.0004701544,0.0006791611,0.000388523,0.0005358276],"domain_scores_gemma":[0.9926215,0.003860875,0.0005577362,0.0003242803,0.002515534,0.0001200425],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003586881,0.0003052547,0.002831192,0.001217125,0.001196129,8.495613e-7,0.004380487,0.000004244952,0.9323665,0.0006874986,0.05112392,0.002299872],"study_design_scores_gemma":[0.002390124,0.0001293877,0.0008204139,0.00008881564,0.0002077902,0.00001185811,0.002415657,0.0008593705,0.8101479,0.001541961,0.1811307,0.0002560418],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9142021,0.0006336716,0.04985683,0.0158321,0.000969149,0.004855683,0.01346337,0.00004757417,0.0001395589],"genre_scores_gemma":[0.9858517,0.00043944,0.0005632335,0.00034184,0.001293055,0.0008995371,0.003109694,0.000099123,0.007402353],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1300068,"threshold_uncertainty_score":0.9994513,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05447454733982696,"score_gpt":0.2816489556524234,"score_spread":0.2271744083125965,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}