{"id":"W2137528784","doi":"10.1002/1521-3773(20011203)40:23<4412::aid-anie4412>3.0.co;2-i","title":"Norbornadiene–Quadricyclane Valence Isomerism for a Tetraphosphorus Derivative The Netherlands Organization for Scientific Research (NOW/CW) is acknowledged for partial support (A.L.S., M.L., K.L.), as are the NSERC of Canada for a scholarship (S.B.C.), and EPSRC for funding phosphaorganometallic chemistry at Sussex University (J.F.N.). Dr. H. Zappey is thanked for the HR-MS spectra and J. C. Slootweg for his initiative.","year":2001,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Quadricyclane; Norbornadiene; Ab initio; Valence (chemistry); Phosphorus; Chemistry; Computational chemistry; Derivative (finance); Physical chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000800441,0.0001058701,0.00005471305,0.0001164605,0.0001302129,0.0001175895,0.0001537299,0.00009578704,0.007664329],"category_scores_gemma":[0.00009522249,0.00005039593,0.0000718043,0.00009224891,0.00008528354,0.000133811,0.00009840015,0.0001550783,0.0003410418],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003228672,"about_ca_system_score_gemma":0.0001626046,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001177812,"about_ca_topic_score_gemma":0.001611581,"domain_scores_codex":[0.9999611,0.000004756115,0.000002223248,0.00001224259,0.000009327245,0.00001035088],"domain_scores_gemma":[0.9999444,0.00001513718,0.000009268319,0.00000955599,0.000008857988,0.00001279011],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001746984,0.0000264318,0.0002772522,0.00004849609,0.000004356306,0.0001052726,0.00003480566,0.0002815235,0.9938406,0.001564009,0.0002528099,0.003389589],"study_design_scores_gemma":[0.0000153741,0.0001829372,0.001542731,0.000003208058,0.000004484515,0.0001677796,0.00001526901,0.001013477,0.993343,0.0001312949,0.003576647,0.000003741432],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948408,0.0002885706,0.0009304679,0.00005686417,0.000009846668,0.000008845119,0.000254625,0.00002169783,0.003588334],"genre_scores_gemma":[0.9950853,0.0002138276,0.0008091528,0.00000683175,0.000001399105,0.000007407927,0.0003217177,0.00001096333,0.003543411],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007664329,"threshold_uncertainty_score":0.02563971,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05447454733982696,"score_gpt":0.2816489556524234,"score_spread":0.2271744083125965,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}