{"id":"W2137840787","doi":"10.1021/ja062796t","title":"Radical/Ion Pair Formation in the Electrochemical Reduction of Arene Sulfenyl Chlorides","year":2006,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Nucleophile; Concerted reaction; Aryl; Acetonitrile; Molecule; Electron transfer; Electrochemistry; Substituent; Ion; Medicinal chemistry; Photochemistry; Dissociation (chemistry); Stereochemistry; Organic chemistry; Physical chemistry; Catalysis; Electrode","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003991524,0.0001856856,0.0004172655,0.00002635227,0.0000743045,0.00002365407,0.0007249188,0.0001362326,0.00003779216],"category_scores_gemma":[0.0004294779,0.0001112753,0.0007400279,0.0006842104,0.0007898313,0.0001717391,0.0000617222,0.001110446,0.000001206872],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004762305,"about_ca_system_score_gemma":0.00007510947,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001306976,"about_ca_topic_score_gemma":0.000001218698,"domain_scores_codex":[0.9978033,0.00003998404,0.0008955605,0.0001658671,0.0007690965,0.0003262321],"domain_scores_gemma":[0.9978805,0.0003870824,0.001186698,0.0003336085,0.0001323637,0.00007969941],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001093511,0.000290256,0.000334506,0.00003427888,0.00003250652,0.000001003919,0.0001539463,0.00002051444,0.989938,0.00004692177,0.008659818,0.0003788914],"study_design_scores_gemma":[0.0004616536,0.00003109795,0.0004287838,0.00007987388,0.0000615972,0.0002845994,0.0005499043,0.0002417683,0.9930422,0.002998626,0.001699046,0.0001208904],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954321,0.0001160303,0.0002337283,0.00359347,0.00005568532,0.00007846769,0.000004482133,0.00001648745,0.0004695774],"genre_scores_gemma":[0.9979617,0.00007144393,0.0009928779,0.0002081468,0.0006997279,0.00001083168,0.000009276181,0.00001750006,0.00002851282],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006960772,"threshold_uncertainty_score":0.4824398,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007356806754006997,"score_gpt":0.2348548275093158,"score_spread":0.2274980207553088,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}