{"id":"W2138071897","doi":"10.1139/v05-148","title":"Time-resolved spectroscopic studies of the photochemistry of some diphenylgermylene (Ph<sub>2</sub>Ge:) precursors","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Flash photolysis; Photodissociation; Trimethylsilyl; Photochemistry; Germane; Radical; Hydrogen atom abstraction; Germanium; Excited state; Derivative (finance); Thermal decomposition; Triplet state; Molecule; Medicinal chemistry; Reaction rate constant; Kinetics; Organic chemistry; Silicon","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009044334,0.0002146496,0.0001365572,0.0001165522,0.0001147259,0.0001668542,0.0002188574,0.0002865362,0.00176601],"category_scores_gemma":[0.0001794706,0.0001259668,0.0001214243,0.0001076438,0.0001461661,0.0002239816,0.0001006057,0.0004165622,0.0002155392],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003286786,"about_ca_system_score_gemma":0.00009817633,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005757611,"about_ca_topic_score_gemma":0.0005526999,"domain_scores_codex":[0.9999503,0.00000706145,0.000001458962,0.00001697967,0.00001149858,0.00001283662],"domain_scores_gemma":[0.9998978,0.00004168734,0.00002690798,0.000005546546,0.00001752055,0.00001048381],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000355722,0.000007136661,0.0001573903,0.00002267784,0.000003160589,0.0000292126,0.00002903684,0.00008891511,0.998801,0.00006176598,0.00001639035,0.0007477588],"study_design_scores_gemma":[0.000004061129,0.0001217302,0.002262154,0.000002198459,0.000006521948,0.00007636897,0.00002952105,0.00101175,0.9959416,0.00002225187,0.0005183429,0.000003512105],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964574,0.0006596895,0.001839124,0.00002359399,0.000006929519,0.000008495684,0.00008305901,0.00003003184,0.0008916261],"genre_scores_gemma":[0.9975121,0.0003556689,0.00124634,0.00001990054,0.000003531199,0.000008604024,0.0000964856,0.00001178067,0.0007454362],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00176601,"threshold_uncertainty_score":0.005907834,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01157461879304125,"score_gpt":0.2129091999494268,"score_spread":0.2013345811563855,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}