{"id":"W2138288808","doi":"10.1039/c1cc11874a","title":"Palladium-catalyzed synthesis of indoles via ammonia cross-coupling–alkyne cyclization","year":2011,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":63,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Methylamine; Alkyne; Catalysis; Hydrazine (antidepressant); Palladium; Ammonia; Coupling (piping); Chemistry; Combinatorial chemistry; Coupling reaction; Ammonia production; Metal; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001774082,0.0003741281,0.0002170494,0.0002713144,0.0002763048,0.0002025089,0.0003817735,0.0002489373,0.001962816],"category_scores_gemma":[0.0001528666,0.0001740156,0.0003051115,0.0001847467,0.0001796744,0.0002352744,0.0003043921,0.0004941697,0.0008360039],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003005966,"about_ca_system_score_gemma":0.000360042,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004679062,"about_ca_topic_score_gemma":0.001216318,"domain_scores_codex":[0.9998698,0.00001592577,0.00001102791,0.00002676799,0.00003098657,0.00004541983],"domain_scores_gemma":[0.999945,0.000009000019,0.00001089364,0.000009347852,0.000009708703,0.00001615443],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005832045,0.00005174504,0.00008417646,0.0001373635,0.0000126802,0.0005417611,0.0000912646,0.0004373398,0.9885993,0.001439305,0.0002012174,0.008345468],"study_design_scores_gemma":[0.00001976751,0.0002939405,0.0008297591,0.00001025568,0.00001466633,0.0004217959,0.00001950046,0.0006943801,0.9851252,0.0001870551,0.01236794,0.00001579626],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9137489,0.005361319,0.04024621,0.0002804218,0.0002301032,0.0003268206,0.000807288,0.0008175725,0.03818132],"genre_scores_gemma":[0.9745553,0.002412405,0.01541024,0.00006121089,0.00002815471,0.00008451503,0.0003726397,0.00005317912,0.00702246],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001962816,"threshold_uncertainty_score":0.006566226,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06359541761346284,"score_gpt":0.3213554833906508,"score_spread":0.257760065777188,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}