{"id":"W2138332575","doi":"10.1016/j.marchem.2014.09.006","title":"A kinetic approach to assess the strengths of ligands bound to soluble Mn(III)","year":2014,"lang":"en","type":"article","venue":"Marine Chemistry","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":64,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université du Québec à Rimouski; McGill University","funders":"Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Manganese; Ligand (biochemistry); Dissociation (chemistry); Reaction rate constant; Pyrophosphate; Porphyrin; Kinetics; Inorganic chemistry; Medicinal chemistry; Physical chemistry; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008740283,0.0006893382,0.0005220099,0.0005416521,0.0003755649,0.0008624529,0.001266843,0.0006398942,0.001971333],"category_scores_gemma":[0.001094345,0.0004929606,0.0003570562,0.0005393717,0.0004819147,0.0005932613,0.0004444583,0.001483383,0.0007122087],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001239062,"about_ca_system_score_gemma":0.0008833409,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004433251,"about_ca_topic_score_gemma":0.006258308,"domain_scores_codex":[0.999549,0.00007552088,0.00002842968,0.000122357,0.0001547182,0.00007003343],"domain_scores_gemma":[0.9993271,0.0002458439,0.0001002444,0.00007942217,0.0001995883,0.00004791641],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002118044,0.00004597257,0.0004102894,0.0001167127,0.00002232195,0.00001374805,0.0000591516,0.0006888448,0.9920412,0.00079359,0.000124067,0.005472247],"study_design_scores_gemma":[0.00001601165,0.0001910942,0.0009567185,0.000007522105,0.00002433973,0.00005758948,0.00006591342,0.006920163,0.9889552,0.0002757973,0.002507742,0.00002188766],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5233853,0.001509198,0.4541906,0.0003265083,0.000165029,0.0007443054,0.001633346,0.001111616,0.01693412],"genre_scores_gemma":[0.8179932,0.00185969,0.1529795,0.0002812118,0.00002398832,0.0007792712,0.001130297,0.0002021242,0.02475081],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004433251,"threshold_uncertainty_score":0.008990049,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0166064356088429,"score_gpt":0.2550438250399712,"score_spread":0.2384373894311283,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}