{"id":"W2138467883","doi":"10.1139/v08-092","title":"Exploring the utility of a new chiral phosphoramidite <i>P</i>,<i>N</i>-ligand derived from (<i>R</i>)-BINOL and 7-azaindole in asymmetric catalysis","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Phosphoramidite; Medicinal chemistry; Ligand (biochemistry); Yield (engineering); Hydrosilylation; Catalysis; Enantioselective synthesis; Alkene; Allylic rearrangement; Hydroboration; Asymmetric hydrogenation; Ketone; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002266498,0.0002064238,0.0004602819,0.0002197839,0.0001293267,0.00003363263,0.0004624408,0.0001135272,0.0002960879],"category_scores_gemma":[0.0004801175,0.0001794783,0.0002087802,0.001112903,0.0002180669,0.0002189685,0.00003521824,0.0004382419,0.000002027093],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001493489,"about_ca_system_score_gemma":0.001300339,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01199184,"about_ca_topic_score_gemma":0.001775141,"domain_scores_codex":[0.9983919,0.00001828267,0.0006924522,0.0002286991,0.0003423336,0.0003263623],"domain_scores_gemma":[0.9982346,0.0001494172,0.0004383595,0.0003704862,0.0001420667,0.0006651017],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003006513,0.0003004024,0.4033127,0.0003780487,0.001542891,0.001742467,0.01833177,0.0001907705,0.422517,0.000006576024,0.005784201,0.1455925],"study_design_scores_gemma":[0.001044207,0.000006957726,0.0143075,0.0000721136,0.00008972,0.0001748433,0.001246627,0.0001236621,0.9804823,0.00006702973,0.002188071,0.0001969777],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910966,0.004492952,0.00003287715,0.0002049107,0.00005324059,0.00003033193,0.00005450234,0.000005754764,0.004028805],"genre_scores_gemma":[0.9988428,0.0004542233,0.00007279775,0.00007052616,0.0001672482,0.000003005239,0.00002536194,0.00001932931,0.0003446866],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5579653,"threshold_uncertainty_score":0.9945874,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03776788244432918,"score_gpt":0.2064869609330854,"score_spread":0.1687190784887562,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}