{"id":"W2138520102","doi":"10.1002/anie.200701215","title":"Reactivity of “Frustrated Lewis Pairs”: Three‐Component Reactions of Phosphines, a Borane, and Olefins","year":2007,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":473,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Frustrated Lewis pair; Borane; Reactivity (psychology); Chemistry; Steric effects; Phosphonium; Reagent; Intramolecular force; Medicinal chemistry; Lewis acids and bases; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001952944,0.0001728309,0.0002204835,0.00007071684,0.00004209843,0.00001411042,0.000157302,0.0001951454,0.001265261],"category_scores_gemma":[0.0001472668,0.0001826192,0.00008653755,0.0001301674,0.0001562164,0.0002026596,0.00005325098,0.000216998,0.00000307934],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001102671,"about_ca_system_score_gemma":0.00004813119,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004907817,"about_ca_topic_score_gemma":0.0001991366,"domain_scores_codex":[0.9987342,0.000003563874,0.0004645539,0.0002662169,0.000367037,0.0001644127],"domain_scores_gemma":[0.9989274,0.0001451737,0.0003541259,0.0002111916,0.0002712696,0.00009087554],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001114755,0.00033786,0.01211955,0.0001894913,0.00008737595,0.000007077511,0.00007068758,0.000001034296,0.9851599,0.0001798863,0.001020841,0.0007148102],"study_design_scores_gemma":[0.0006985549,0.00001559002,0.01846291,0.0001356417,0.00003719561,0.00003281236,0.0001412314,0.00002777848,0.9775676,0.0003051709,0.002421679,0.0001538595],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9834647,0.0001224586,0.0004929546,0.0003406876,0.0002744212,0.00004762159,0.0002666657,0.00006662845,0.01492385],"genre_scores_gemma":[0.9984725,0.0001614163,0.0001676537,0.00003155621,0.0004716165,0.000005714187,0.0004346187,0.0000203498,0.0002345704],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01500779,"threshold_uncertainty_score":0.9996477,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01404084262872277,"score_gpt":0.2491442801536644,"score_spread":0.2351034375249416,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}