{"id":"W2138527038","doi":"10.1080/10426507.2012.710674","title":"The Reaction of Ketenylidenetriphenylphosphorane (Ph<sub>3</sub>P˭C˭C˭O) with Acidic H‒E (E˭O, N) Bonds","year":2012,"lang":"en","type":"article","venue":"Phosphorus, sulfur, and silicon and the related elements","topic":"Phosphorus compounds and reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University","funders":"","keywords":"Chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008870326,0.0003852088,0.0004547497,0.00005662799,0.0009096828,0.00009803577,0.000246184,0.0002255303,0.00004090499],"category_scores_gemma":[0.00006597762,0.0002123262,0.0001204902,0.0003009057,0.0008124117,0.0003067165,0.0001304174,0.000560193,0.00001478883],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006798036,"about_ca_system_score_gemma":0.00005216874,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005183427,"about_ca_topic_score_gemma":0.00004618625,"domain_scores_codex":[0.9977559,0.00007095234,0.0006943286,0.000366309,0.000436541,0.0006759826],"domain_scores_gemma":[0.9982761,0.0003469658,0.000447645,0.0005662103,0.0001067924,0.0002563516],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003149987,0.0005671575,0.03309496,0.000144893,0.001864811,0.000009034799,0.002583172,0.000004745947,0.8029724,0.02184079,0.001234874,0.1325331],"study_design_scores_gemma":[0.007577309,0.0001787685,0.01267555,0.0001877124,0.000623643,0.000236443,0.003040677,0.000283186,0.9369913,0.002147594,0.0354309,0.0006268501],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9568685,0.03374057,0.000004389223,0.0004837416,0.0002327789,0.0002725733,0.00002036202,0.00007416784,0.008302884],"genre_scores_gemma":[0.9537001,0.04508034,0.00001015041,0.00007104599,0.00006808576,0.00006435686,0.00003155036,0.00004558648,0.0009287987],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1340189,"threshold_uncertainty_score":0.8658412,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006442110276240273,"score_gpt":0.2065774917313392,"score_spread":0.2001353814550989,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}