{"id":"W2138527038","doi":"10.1080/10426507.2012.710674","title":"The Reaction of Ketenylidenetriphenylphosphorane (Ph<sub>3</sub>P˭C˭C˭O) with Acidic H‒E (E˭O, N) Bonds","year":2012,"lang":"en","type":"article","venue":"Phosphorus, sulfur, and silicon and the related elements","topic":"Phosphorus compounds and reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University","funders":"","keywords":"Chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001128303,0.0002825371,0.00008480628,0.00008132429,0.000128479,0.0001527766,0.0002017344,0.0002104157,0.001572534],"category_scores_gemma":[0.0001178947,0.0001167188,0.0001041796,0.00008791525,0.0001349814,0.0002369956,0.0001786317,0.0002510944,0.0003745352],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001370488,"about_ca_system_score_gemma":0.0001511618,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003927137,"about_ca_topic_score_gemma":0.0007473212,"domain_scores_codex":[0.9999171,0.00001382183,0.000003955725,0.00001697535,0.00001721389,0.00003099738],"domain_scores_gemma":[0.9999415,0.00001591225,0.00001519226,0.000006758289,0.000007027643,0.00001366784],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001383129,0.00001942296,0.0002411305,0.00009718936,0.0000103221,0.0001444188,0.00003816014,0.000150479,0.9960201,0.0002032609,0.00006703831,0.002870105],"study_design_scores_gemma":[0.000006339355,0.0001354739,0.000666058,0.000002600634,0.000003668563,0.0001351192,0.00001050515,0.0001874185,0.9973327,0.0000191406,0.001498285,0.000002759083],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9909564,0.0008928342,0.002009297,0.00004277735,0.00002477114,0.00002785764,0.0001406812,0.00005041192,0.005854908],"genre_scores_gemma":[0.9950851,0.0006145716,0.001422782,0.00002238466,0.000005152121,0.0000142208,0.0001650552,0.000008707501,0.002662001],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001572534,"threshold_uncertainty_score":0.005260587,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006442110276240273,"score_gpt":0.2065774917313392,"score_spread":0.2001353814550989,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}