{"id":"W2138740144","doi":"10.1351/pac-con-09-11-27","title":"Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions","year":2010,"lang":"en","type":"article","venue":"Pure and Applied Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung","keywords":"Chemistry; Hydroamination; Catalysis; Transition metal; Combinatorial chemistry; Oxidation state; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003408413,0.0004597417,0.0003189514,0.0002113035,0.0001996743,0.0002885058,0.0007003399,0.0005223368,0.001468778],"category_scores_gemma":[0.0002447552,0.0001883079,0.0002458078,0.0001382239,0.0002201582,0.0004088251,0.0003691869,0.0004073185,0.0006913494],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000281969,"about_ca_system_score_gemma":0.0002217652,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002981977,"about_ca_topic_score_gemma":0.0009978461,"domain_scores_codex":[0.9998065,0.00002771489,0.00001921828,0.00004171391,0.00006763486,0.00003735173],"domain_scores_gemma":[0.9999083,0.00001659602,0.00002458761,0.00001378787,0.00001775233,0.00001890523],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009514936,0.00005725327,0.0001724221,0.0002956671,0.00002102403,0.000225578,0.00009232022,0.0003380273,0.9847552,0.002309839,0.0003866636,0.01125074],"study_design_scores_gemma":[0.00003567525,0.0004248973,0.0004590011,0.00001221001,0.00001463357,0.0003280519,0.00001603599,0.001150682,0.989175,0.0001907583,0.008174983,0.00001809407],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9165203,0.007193911,0.04421774,0.0002549412,0.0002942636,0.0004021965,0.0004635626,0.0003917837,0.03026133],"genre_scores_gemma":[0.9764593,0.002448359,0.0164957,0.00008492512,0.00004407568,0.00008154949,0.0002193037,0.0000428233,0.00412384],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001468778,"threshold_uncertainty_score":0.004913568,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007760294424219445,"score_gpt":0.2258614818801866,"score_spread":0.2181011874559671,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}