{"id":"W2139038619","doi":"10.1021/jo062655+","title":"Aza-Morita−Baylis−Hillman Reactions and Cyclizations of Conjugated Dienes Activated by Sulfone, Ester, and Keto Groups","year":2007,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Adduct; Conjugated system; Sulfone; Intramolecular force; Medicinal chemistry; Aldimine; Imine; Baylis–Hillman reaction; Addition reaction; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004812213,0.0007983426,0.0002940311,0.0004703384,0.0002992332,0.0002231756,0.0002979289,0.0004214075,0.002136295],"category_scores_gemma":[0.0002273221,0.0002692842,0.0004397015,0.0002866553,0.0002546563,0.0005476027,0.0003289096,0.0005536453,0.0005719594],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002589355,"about_ca_system_score_gemma":0.0002713421,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002251264,"about_ca_topic_score_gemma":0.000704256,"domain_scores_codex":[0.9997492,0.00005287383,0.0000189073,0.00004785006,0.00003849666,0.00009261753],"domain_scores_gemma":[0.9999083,0.0000127258,0.00002062618,0.00001953893,0.00001549828,0.00002325875],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001273324,0.00005912223,0.0002243673,0.0001424961,0.00002694846,0.0003039745,0.0002055692,0.0002494003,0.9882171,0.00252768,0.0001292201,0.007786884],"study_design_scores_gemma":[0.0000166863,0.0004076248,0.000708541,0.000006540184,0.00001142847,0.0002777268,0.00002556952,0.0002667255,0.9928045,0.0001463011,0.005315386,0.00001293848],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9687861,0.003806761,0.01591662,0.0001398059,0.0001057361,0.0001840513,0.0002519446,0.0001779346,0.0106311],"genre_scores_gemma":[0.9790432,0.002456501,0.01163482,0.00005943567,0.00002422816,0.0001450221,0.0003373235,0.00003460246,0.006264838],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002136295,"threshold_uncertainty_score":0.007146597,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007674425991041963,"score_gpt":0.2320050403488164,"score_spread":0.2243306143577745,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}