{"id":"W2139243296","doi":"10.1139/v02-182","title":"Ryanoids and related compounds Chemoselective electrocatalytic hydrogenation of alkyl α-pyrrole carboxylates: Selective hydrogenation of ryanodine","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; British Heart Foundation; Imperial College London; National Science Foundation","keywords":"Chemistry; Alkyl; Pyrrole; Catalysis; Ryanodine receptor; Organic chemistry; Catalytic hydrogenation; Molecule; Derivative (finance); Combinatorial chemistry; Calcium","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001484596,0.0002088861,0.0002469949,0.00008217698,0.00009457736,0.0001577994,0.0001967684,0.0002654233,0.0005991983],"category_scores_gemma":[0.0001494144,0.0001278292,0.0001702926,0.00009144045,0.0001916982,0.0003345933,0.0001211227,0.0003206769,0.000203229],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001797649,"about_ca_system_score_gemma":0.0001108925,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004111781,"about_ca_topic_score_gemma":0.0006275959,"domain_scores_codex":[0.9998943,0.00001285491,0.000006892232,0.00002417974,0.00004173875,0.00002005051],"domain_scores_gemma":[0.9999231,0.00002981396,0.00001517516,0.000008823275,0.00001473014,0.000008280829],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004682227,0.00000895827,0.00003596245,0.00004937284,0.000004389856,0.00005826826,0.00001605886,0.00007879012,0.9982439,0.0000847133,0.00001514692,0.001357656],"study_design_scores_gemma":[0.00000463835,0.00008825851,0.0002553891,0.000001035562,0.000003087524,0.000148876,0.000008962448,0.0001981333,0.9986115,0.0000211651,0.0006570541,0.000001943211],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.985404,0.005715344,0.005565631,0.0001018514,0.00003225151,0.00004039298,0.00008174973,0.00003012534,0.003028705],"genre_scores_gemma":[0.9902039,0.002993744,0.003190298,0.0000328737,0.000008819001,0.00001547597,0.0001164945,0.00001428474,0.003424201],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005991983,"threshold_uncertainty_score":0.002004564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005199135636757828,"score_gpt":0.1856968708979737,"score_spread":0.1804977352612158,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}