{"id":"W2139336886","doi":"10.1039/b9pp00186g","title":"Bio-supramolecular photochirogenesis with molecular chaperone: enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate mediated by prefoldin","year":2010,"lang":"en","type":"article","venue":"Photochemical & Photobiological Sciences","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":21,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Victoria","funders":"RIKEN; Japan Society for the Promotion of Science; Natural Sciences and Engineering Research Council of Canada; University of Victoria; Sumitomo Foundation","keywords":"Supramolecular chemistry; Steric effects; Chemistry; Chaperone (clinical); Enantiomer; Head (geology); Stereochemistry; Biophysics; Crystallography; Biology; Crystal structure; Medicine","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006788468,0.0005418648,0.000705884,0.00008215694,0.0003227653,0.00011706,0.001303589,0.0004409375,0.002078772],"category_scores_gemma":[0.0004845074,0.0003570472,0.0001843833,0.0007969828,0.0028947,0.0002297925,0.000266997,0.0004575264,0.00003417745],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003940543,"about_ca_system_score_gemma":0.0001516412,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001968004,"about_ca_topic_score_gemma":0.000005633315,"domain_scores_codex":[0.9960452,0.0001183381,0.0007782886,0.001293432,0.0008142978,0.0009504103],"domain_scores_gemma":[0.998166,0.0002549803,0.0005199207,0.0005285157,0.0001587434,0.0003719044],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001267847,0.0002946285,0.003000945,0.00003487777,0.00001982444,0.000008191816,0.00005945341,0.00000655336,0.996276,0.00006758594,0.00004558966,0.00005956634],"study_design_scores_gemma":[0.0006681521,0.0002994454,0.0002857449,0.0000671051,0.00004220486,0.00003222422,0.00007279725,0.0008582636,0.9968342,0.0001744783,0.0001158148,0.0005496338],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967502,0.0001548592,0.0004796786,0.0000601002,0.0001317629,0.001186888,0.0001850967,0.0001863158,0.0008650379],"genre_scores_gemma":[0.9956138,0.00003306155,0.00353306,0.0001872591,0.00003621896,0.0004247766,0.0001325775,0.00002895319,0.00001026072],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003053381,"threshold_uncertainty_score":0.9998881,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006428594826083134,"score_gpt":0.2268840279207859,"score_spread":0.2204554330947028,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}