{"id":"W2139427787","doi":"10.1002/masy.201300048","title":"An In‐Situ <scp>NMR</scp> Study of Radical Copolymerization Kinetics of Acrylamide and Non‐<scp>I</scp>onized Acrylic Acid in Aqueous Solution","year":2013,"lang":"en","type":"article","venue":"Macromolecular Symposia","topic":"NMR spectroscopy and applications","field":"Physics and Astronomy","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Monomer; Copolymer; Acrylic acid; Aqueous solution; Acrylamide; Polymer chemistry; Kinetics; Isothermal process; Reactivity (psychology); Chemistry; Aqueous two-phase system; Materials science; Polymer; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000125539,0.0002481953,0.000424426,0.0001854016,0.00006522093,0.00005666038,0.0002694041,0.000103669,0.00001204947],"category_scores_gemma":[0.00002186945,0.0002680038,0.00006403081,0.0005239609,0.0001411949,0.0001652991,0.00009426499,0.0002127719,0.000007979609],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003415644,"about_ca_system_score_gemma":0.00004140946,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001039222,"about_ca_topic_score_gemma":0.0000991173,"domain_scores_codex":[0.9982313,0.0001506593,0.0005760482,0.0004132727,0.000247197,0.0003815047],"domain_scores_gemma":[0.9990034,0.00008679507,0.0002658226,0.0004507755,0.0000723912,0.0001208579],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000004120913,0.00145926,0.03166229,0.00002243862,0.00004226987,0.000004692964,0.001913026,0.0001149624,0.9615713,0.002105367,0.00002745587,0.001072867],"study_design_scores_gemma":[0.002245697,0.0005491622,0.06439628,0.00004953795,0.00006046829,0.000003482213,0.00190627,0.002835693,0.9267541,0.00102431,0.00008863733,0.00008631813],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.981383,0.0002605446,0.01603294,0.00003090414,0.0000310265,0.00103048,0.0000166768,0.00002040654,0.001194032],"genre_scores_gemma":[0.9987312,0.00001738174,0.0008398112,0.00002316965,0.00004657834,0.0001942355,0.00008442947,0.00003638181,0.0000268181],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0348171,"threshold_uncertainty_score":0.9999772,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004269141313532764,"score_gpt":0.2597282525113216,"score_spread":0.2554591111977889,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}