{"id":"W2139674193","doi":"10.1002/chin.200330102","title":"Conjugate Additions of o‐Iodoanilines and Methyl Anthranilates to Acetylenic Sulfones. A New Route to Quinolones Including First Syntheses of Two Alkaloids from the Medicinal Herb Ruta chalepensis.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Reactivity of Sulfur-Containing Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Conjugate; Herb; Stereochemistry; Organic chemistry; Medicinal herbs; Traditional medicine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002420031,0.00052284,0.0002582914,0.0002874772,0.0002115033,0.0002170743,0.0004870282,0.0003329901,0.003952005],"category_scores_gemma":[0.0001921163,0.0002680365,0.0002504073,0.0002618783,0.0003322319,0.0004020439,0.0003500246,0.0003972284,0.0009779534],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003254712,"about_ca_system_score_gemma":0.0003021968,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006349155,"about_ca_topic_score_gemma":0.001511426,"domain_scores_codex":[0.9998571,0.0000337372,0.0000118291,0.00002509646,0.00002469001,0.00004759537],"domain_scores_gemma":[0.999898,0.00001490458,0.00003460643,0.00001951841,0.00001311957,0.00001990899],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007282126,0.0000847089,0.000297182,0.000275464,0.00004190712,0.0004527778,0.0001832788,0.0006155817,0.9796679,0.003444555,0.0007601799,0.01344837],"study_design_scores_gemma":[0.00008259128,0.0009939889,0.0005590154,0.000009123256,0.00002129387,0.0002825948,0.0000196077,0.0003098971,0.9901716,0.0001739526,0.007363928,0.0000124296],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9194664,0.005513907,0.02668765,0.0003774173,0.0004344351,0.0003225614,0.0007538554,0.0008670536,0.04557668],"genre_scores_gemma":[0.9854215,0.002027743,0.004709937,0.00005723537,0.00003659286,0.00005488531,0.0002363254,0.00004369912,0.00741203],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003952005,"threshold_uncertainty_score":0.01322073,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04520050669352361,"score_gpt":0.2782945274014988,"score_spread":0.2330940207079752,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}