{"id":"W2139674193","doi":"10.1002/chin.200330102","title":"Conjugate Additions of o‐Iodoanilines and Methyl Anthranilates to Acetylenic Sulfones. A New Route to Quinolones Including First Syntheses of Two Alkaloids from the Medicinal Herb Ruta chalepensis.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Reactivity of Sulfur-Containing Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Conjugate; Herb; Stereochemistry; Organic chemistry; Medicinal herbs; Traditional medicine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003199119,0.0003088982,0.0006801301,0.00008015183,0.0002043149,0.00004670323,0.0003706427,0.000140691,0.0005885666],"category_scores_gemma":[0.00158534,0.0002299962,0.0001477594,0.0002098129,0.00025664,0.0001715102,0.000187902,0.0001790051,0.000009615257],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006394274,"about_ca_system_score_gemma":0.0001388322,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00205953,"about_ca_topic_score_gemma":0.000609452,"domain_scores_codex":[0.9984173,0.000003555102,0.0005644164,0.0003357436,0.000337272,0.0003416938],"domain_scores_gemma":[0.9966764,0.002168176,0.0002804296,0.000515654,0.000136946,0.0002223341],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003682643,0.0002233826,0.009160627,0.0004177379,0.0008642676,0.00001327951,0.01674755,0.00001600295,0.8422542,0.0007082312,0.006680048,0.1225465],"study_design_scores_gemma":[0.0006540559,0.00006086993,0.001557979,0.001236019,0.0001614506,0.00003703542,0.00327067,0.00001468098,0.9719806,0.0002592246,0.02045843,0.0003089944],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9705796,0.001647676,0.00001521589,0.002401967,0.000131833,0.0001733556,0.000138221,0.00005562744,0.02485648],"genre_scores_gemma":[0.9978924,0.0002662677,0.0005425068,0.0001685809,0.0002141869,0.00002357277,0.00002323467,0.00003052358,0.0008387184],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1297264,"threshold_uncertainty_score":0.9378973,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04520050669352361,"score_gpt":0.2782945274014988,"score_spread":0.2330940207079752,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}