{"id":"W2140249587","doi":"10.1071/ch14577","title":"Synthesis of Sterically Demanding Bis(phosphinimine) Dibenzofuran Ligands and Subsequent Zinc Metalation*","year":2014,"lang":"en","type":"article","venue":"Australian Journal of Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"","keywords":"Dibenzofuran; Steric effects; Chemistry; Zinc; Pincer ligand; Cationic polymerization; Phosphine; Ligand (biochemistry); Medicinal chemistry; Pincer movement; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001395965,0.0004166098,0.000315167,0.0002123898,0.0002345083,0.0002987253,0.000697808,0.0003854611,0.002651367],"category_scores_gemma":[0.0001953511,0.0002258068,0.0001564701,0.0002682244,0.0001430872,0.0002431302,0.0003850655,0.00046827,0.001058675],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005667517,"about_ca_system_score_gemma":0.0003167892,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009520511,"about_ca_topic_score_gemma":0.0020603,"domain_scores_codex":[0.9998776,0.00001650977,0.00001083296,0.00002355357,0.00003239515,0.00003910721],"domain_scores_gemma":[0.999936,0.000008369637,0.00001427865,0.000007776505,0.00001166399,0.00002189765],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001700572,0.00007512206,0.0001393918,0.0002515135,0.0000151828,0.0002174558,0.00008573588,0.001034359,0.9839152,0.001928587,0.00045153,0.01171596],"study_design_scores_gemma":[0.00006524051,0.0004113402,0.0004458713,0.00001348006,0.00001184759,0.0002571417,0.00002068549,0.001666951,0.9846404,0.0001419151,0.0122986,0.00002656434],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9528476,0.001914741,0.0242239,0.0002035001,0.00006885365,0.000413209,0.00107494,0.0005725752,0.01868078],"genre_scores_gemma":[0.9743111,0.001025365,0.01846601,0.00008870982,0.00001429586,0.0001551611,0.0007624279,0.00006737909,0.005109532],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002651367,"threshold_uncertainty_score":0.008869708,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01733423799839269,"score_gpt":0.2325078268874624,"score_spread":0.2151735888890697,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}