{"id":"W2140925678","doi":"10.1002/anie.200802034","title":"Tuning of Electrogenerated Silole Chemiluminescence","year":2008,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":84,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Electrochemiluminescence; Thiophene; Chemiluminescence; Chromophore; Electrochemistry; Photochemistry; Combinatorial chemistry; Chemistry; Materials science; Organic chemistry; Electrode; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003511062,0.0005124423,0.0001419595,0.000244216,0.0001123257,0.0004192972,0.0004759611,0.0004285811,0.001145006],"category_scores_gemma":[0.0005651712,0.0002058605,0.000182888,0.0001671128,0.0002928461,0.0003510698,0.0002467002,0.0005504704,0.0003665101],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003324759,"about_ca_system_score_gemma":0.0001588648,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001052033,"about_ca_topic_score_gemma":0.0002178689,"domain_scores_codex":[0.9997531,0.00004738016,0.00001729448,0.00006762311,0.00007230009,0.00004230072],"domain_scores_gemma":[0.9997543,0.0001034821,0.00004950515,0.00001733598,0.00005280002,0.0000226233],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002520774,0.000009649149,0.00003099833,0.00002213039,0.000002385632,0.00001872282,0.00001370047,0.00008387928,0.9984243,0.0001942365,0.00003273052,0.001142033],"study_design_scores_gemma":[0.000006202761,0.00002936911,0.00009281618,0.000001133853,0.00000165029,0.00001758699,0.000003214383,0.0006519479,0.9986988,0.00002956419,0.0004653367,0.00000232895],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9597656,0.0009585214,0.03503076,0.0002338126,0.00006868651,0.00005968265,0.0001822138,0.0005068736,0.003193955],"genre_scores_gemma":[0.9863285,0.0005771224,0.01114696,0.000151765,0.0000189181,0.00004891679,0.0001667076,0.00006205597,0.001499014],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001145006,"threshold_uncertainty_score":0.003830433,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01275751354580943,"score_gpt":0.2602254857537269,"score_spread":0.2474679722079175,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}