{"id":"W2140925678","doi":"10.1002/anie.200802034","title":"Tuning of Electrogenerated Silole Chemiluminescence","year":2008,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":84,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Electrochemiluminescence; Thiophene; Chemiluminescence; Chromophore; Electrochemistry; Photochemistry; Combinatorial chemistry; Chemistry; Materials science; Organic chemistry; Electrode; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005917054,0.00009448303,0.00009364751,0.00004661311,0.00004556992,0.000004444532,0.0001215958,0.00008663087,0.00001045689],"category_scores_gemma":[0.0000856861,0.00009150863,0.00007849921,0.00009759582,0.00009414613,0.000007880763,0.00003649748,0.00005323756,0.000001390093],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001966589,"about_ca_system_score_gemma":0.00003146808,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008945584,"about_ca_topic_score_gemma":0.000002984576,"domain_scores_codex":[0.9993573,0.000007827904,0.0001709107,0.0001972498,0.000162829,0.0001038852],"domain_scores_gemma":[0.9994405,0.000005830398,0.0001141109,0.0001305608,0.0002786982,0.00003028578],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003753865,0.00004292479,0.0008069288,0.000003210951,0.00004139613,0.000002943779,0.000009439917,0.000003106452,0.9932402,0.00001448729,0.005611581,0.0001862572],"study_design_scores_gemma":[0.0001664812,0.00005508924,0.0002339683,0.00001572341,0.00000932384,0.0000505328,0.00001123758,0.00004580878,0.9940005,0.00004194648,0.005267121,0.0001022745],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9838808,0.0001512847,0.0121306,0.0002115606,0.0001728852,0.00005817068,0.00003834721,0.00004204438,0.003314343],"genre_scores_gemma":[0.9952884,0.0003753038,0.002184425,0.0001373721,0.0006069998,0.000006256966,0.0008647519,0.000009764882,0.0005267194],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01140764,"threshold_uncertainty_score":0.3731614,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01275751354580943,"score_gpt":0.2602254857537269,"score_spread":0.2474679722079175,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}