{"id":"W2141076090","doi":"10.1039/b211789d","title":"Rhodium catalysed dehydrogenative borylation of vinylarenes and 1,1-disubstituted alkenes without sacrificial hydrogenation—a route to 1,1-disubstituted vinylboronates","year":2003,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":162,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Borylation; Alkene; Hydroboration; Chemistry; Alkyne; Rhodium; Substrate (aquarium); Catalysis; Medicinal chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000183777,0.000435713,0.0003091104,0.0001847837,0.0001485267,0.00028569,0.000474526,0.0003112606,0.001250188],"category_scores_gemma":[0.0001788614,0.0003308462,0.0002274123,0.0001395017,0.0002432387,0.0005164532,0.000374232,0.0004706196,0.000715424],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000348593,"about_ca_system_score_gemma":0.000276675,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006506798,"about_ca_topic_score_gemma":0.00126279,"domain_scores_codex":[0.9998645,0.00002145631,0.00001279217,0.00002805121,0.00002631598,0.00004691027],"domain_scores_gemma":[0.9999323,0.000009016741,0.00001865498,0.00001369957,0.000007640465,0.00001873764],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007951834,0.0000162681,0.00005748614,0.00006230899,0.000007984789,0.00007170325,0.00003435461,0.0001471447,0.9964454,0.0005851274,0.00005453044,0.002438372],"study_design_scores_gemma":[0.00001603415,0.00008821998,0.0002067695,0.000002545745,0.000007078666,0.0001188521,0.00001055275,0.0002583853,0.9975551,0.00005595439,0.001673738,0.000006770124],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9819146,0.002316661,0.007512763,0.0001476561,0.0000650323,0.00004753084,0.0001953049,0.0001965748,0.007603898],"genre_scores_gemma":[0.9912021,0.00121678,0.003931365,0.00002576479,0.000008130448,0.00001337983,0.000174232,0.00004750309,0.003380635],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001250188,"threshold_uncertainty_score":0.004182279,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02317397915392828,"score_gpt":0.2773655100906273,"score_spread":0.254191530936699,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}