{"id":"W2141235471","doi":"10.1007/s00216-010-4038-4","title":"Direct analysis of polyols using 3-nitrophenylboronic acid in capillary electrophoresis: thermodynamic and electrokinetic principles of molecular recognition","year":2010,"lang":"en","type":"article","venue":"Analytical and Bioanalytical Chemistry","topic":"Microfluidic and Capillary Electrophoresis Applications","field":"Engineering","cited_by":13,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University","funders":"Japan Society for the Promotion of Science","keywords":"Chemistry; Capillary electrophoresis; Electrokinetic phenomena; Polyol; Boronic acid; Micellar electrokinetic chromatography; Selectivity; Chromatography; Combinatorial chemistry; Analytical Chemistry (journal); Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008893225,0.0005299796,0.0004368983,0.0003477116,0.0003655696,0.001009692,0.0009373887,0.0008092255,0.0003372041],"category_scores_gemma":[0.0005956375,0.0005308829,0.0002622438,0.0002676093,0.001076436,0.0009929007,0.0004528439,0.001071936,0.000284684],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006220719,"about_ca_system_score_gemma":0.0008330204,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001054438,"about_ca_topic_score_gemma":0.002605788,"domain_scores_codex":[0.9995292,0.0001209289,0.00001599178,0.00009197149,0.0001844033,0.00005747355],"domain_scores_gemma":[0.9997461,0.000125255,0.00002739301,0.00001857804,0.00004851331,0.0000340673],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006418638,0.0000170317,0.00009224865,0.00004585982,0.000004634572,0.00001861963,0.0000301996,0.0001185027,0.9958663,0.001061348,0.00002768809,0.002653325],"study_design_scores_gemma":[0.000005718305,0.00005108519,0.0001906041,0.000003026191,0.000005183983,0.00007571064,0.000008541842,0.002572449,0.9965521,0.0002013639,0.0003243584,0.000009738934],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7595103,0.005724699,0.2308838,0.0004685455,0.0001326739,0.0001470139,0.00008500028,0.0003812447,0.002666818],"genre_scores_gemma":[0.9028904,0.003356094,0.09005702,0.0002205464,0.00004068338,0.0001491873,0.00007386033,0.00007106426,0.003141115],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001054438,"threshold_uncertainty_score":0.004703224,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007211944609436412,"score_gpt":0.207818698816962,"score_spread":0.2006067542075256,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}