{"id":"W2141340306","doi":"10.1039/c4cc08993f","title":"Easy and quantitative access to Fe(<scp>ii</scp>) and Fe(<scp>iii</scp>) di(aryl)alkynylphosphine oxides featuring [Fe(dppe)Cp*] endgroups: terminal PO functionality blocks the dimerisation of the Fe(<scp>iii</scp>) derivatives","year":2014,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"Agence Nationale de la Recherche","keywords":"Aryl; Terminal (telecommunication); Chemistry; Computer science; Organic chemistry; Computer network","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001062327,0.0003698087,0.0001112031,0.0001561341,0.0001324666,0.0001619868,0.0001562534,0.0002511262,0.001683244],"category_scores_gemma":[0.0001379922,0.0001616054,0.00006827075,0.0001129733,0.000207104,0.0002375795,0.0002174194,0.0006059154,0.0003814833],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001197997,"about_ca_system_score_gemma":0.00009280963,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002004673,"about_ca_topic_score_gemma":0.0005823392,"domain_scores_codex":[0.9999311,0.000007793774,0.000004283382,0.00002376299,0.00001859261,0.00001445822],"domain_scores_gemma":[0.9999355,0.00001317032,0.00001940301,0.000008193829,0.00001291875,0.00001085893],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002618085,0.000004645576,0.00003666511,0.00003030776,0.000001248122,0.00002072138,0.00001707924,0.00001885806,0.9981967,0.0001012615,0.00004247974,0.001503924],"study_design_scores_gemma":[0.000004323797,0.00004858513,0.0004731608,0.000002609169,0.000002359203,0.00009988064,0.000009862868,0.0001115345,0.9977337,0.00002772876,0.001483937,0.000002211806],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.972369,0.001212945,0.01792376,0.0001330986,0.00003445564,0.00005996614,0.0005590052,0.000235592,0.007472234],"genre_scores_gemma":[0.9881412,0.0006594681,0.007182352,0.00003806587,0.0000120992,0.00003600225,0.0003712178,0.00004467884,0.003515002],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001683244,"threshold_uncertainty_score":0.00563097,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03726693960209757,"score_gpt":0.2986892813522504,"score_spread":0.2614223417501528,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}