{"id":"W2141501081","doi":"10.1039/b100492l","title":"Mechanistic aspects of enzymatic carbohydrate epimerization","year":2002,"lang":"en","type":"review","venue":"Natural Product Reports","topic":"Diet, Metabolism, and Disease","field":"Medicine","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Mutarotation; Stereocenter; Epimer; Enzyme; Chemistry; Carbohydrate; Stereochemistry; Sugar; Biochemistry; Biocatalysis; Cofactor; Reaction mechanism; Catalysis; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003604581,0.0005279562,0.002529087,0.000354838,0.00005159484,0.00002343048,0.0001083982,0.000214448,0.0002077649],"category_scores_gemma":[0.002159175,0.000380737,0.0006261451,0.0007547801,0.00007139794,0.00009793468,0.00005516604,0.0004923875,0.0000432986],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009164214,"about_ca_system_score_gemma":0.0005844628,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001944246,"about_ca_topic_score_gemma":9.479878e-7,"domain_scores_codex":[0.9965742,0.0001221373,0.001428856,0.0008220381,0.0007118892,0.0003408827],"domain_scores_gemma":[0.9966881,0.00004582595,0.00149053,0.00121393,0.0003343569,0.0002272435],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00001527526,0.0003425939,0.000004277096,0.07443131,0.0004515346,0.003254986,0.00006581525,7.187433e-7,0.0001864188,0.0006664336,0.001659683,0.9189209],"study_design_scores_gemma":[0.0003033329,0.0001160425,0.00005393239,0.01740379,0.01222707,0.003149823,0.000009596761,0.00002350939,0.0003988803,0.001145484,0.9643613,0.0008073063],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0001137033,0.9901296,0.000004992767,0.00003127205,0.002675012,0.001913613,0.00001254957,0.0001172135,0.005002019],"genre_scores_gemma":[0.02265936,0.9724063,0.0001948621,0.00004219714,0.001001918,0.00006313525,0.0005434632,0.00009416168,0.002994582],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9627016,"threshold_uncertainty_score":0.9998645,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03222242399072708,"score_gpt":0.3168219699835354,"score_spread":0.2845995459928083,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}