{"id":"W2141517019","doi":"10.1002/anie.200903360","title":"Unexpected Acid Catalysis in Reactions of Peroxyl Radicals with Phenols","year":2009,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":73,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Radical; Reactivity (psychology); Catalysis; Phenols; Photochemistry; Phenol; Counterintuitive; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003629257,0.0004338484,0.0002269261,0.0001699195,0.0001734498,0.0004488753,0.0003949072,0.000536665,0.0009264855],"category_scores_gemma":[0.0004974251,0.0002190104,0.0002145684,0.00009915443,0.0003950056,0.0005801752,0.0005555774,0.0008967804,0.0004015708],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000146834,"about_ca_system_score_gemma":0.0001016875,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009734646,"about_ca_topic_score_gemma":0.0001059955,"domain_scores_codex":[0.9997454,0.000058403,0.00001145951,0.00005041621,0.00007352099,0.00006075894],"domain_scores_gemma":[0.9998502,0.00005890424,0.00002920335,0.00001548281,0.00001890726,0.000027285],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001617789,0.00003231664,0.0001832548,0.0001552095,0.00001483159,0.000290626,0.00008355855,0.0001621986,0.9928553,0.002179029,0.0002367351,0.003645319],"study_design_scores_gemma":[0.0000285952,0.0001894405,0.0002971663,0.000004573562,0.000009190665,0.0001752539,0.00002318893,0.000520631,0.9958385,0.0006116109,0.002294874,0.000006991022],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9763715,0.003830895,0.01260447,0.0005770106,0.0002312435,0.00006419819,0.0001161422,0.0001618764,0.006042655],"genre_scores_gemma":[0.9966044,0.0007628382,0.001341783,0.00009925418,0.00003781608,0.00002381721,0.00004452094,0.00001452519,0.001071031],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009264855,"threshold_uncertainty_score":0.003099442,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00998712028710747,"score_gpt":0.2437942272246095,"score_spread":0.233807106937502,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}