{"id":"W2141517019","doi":"10.1002/anie.200903360","title":"Unexpected Acid Catalysis in Reactions of Peroxyl Radicals with Phenols","year":2009,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":73,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Radical; Reactivity (psychology); Catalysis; Phenols; Photochemistry; Phenol; Counterintuitive; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007253164,0.0001280632,0.0001869815,0.000117781,0.00003316922,0.00002213833,0.0001891934,0.0001025798,0.001447888],"category_scores_gemma":[0.0001030138,0.0001152892,0.00007630049,0.0001893556,0.00008100043,0.0002350142,0.0000132356,0.0001676973,0.000009278609],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001158568,"about_ca_system_score_gemma":0.00003828028,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009799472,"about_ca_topic_score_gemma":0.00003631024,"domain_scores_codex":[0.9988938,0.000006173397,0.0003344213,0.0002316474,0.0003801427,0.0001537994],"domain_scores_gemma":[0.9994252,0.00004254838,0.0001731666,0.0001713593,0.0001242119,0.0000634571],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007677855,0.0003428818,0.000744105,0.00002069876,0.00005667226,0.00001788907,0.0001041618,0.0000181525,0.9954262,0.0004385045,0.001323274,0.0014307],"study_design_scores_gemma":[0.000808871,0.00002955012,0.002923115,0.0002200162,0.00002139452,0.00002302202,0.0001249736,0.00008988498,0.9918708,0.0007431059,0.003012612,0.0001326246],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9452684,0.000179014,0.00116029,0.002188126,0.0001764201,0.00006197207,0.0001095906,0.00008850535,0.05076768],"genre_scores_gemma":[0.997833,0.0001033384,0.0003345163,0.00008269196,0.0005126921,0.00001498307,0.0005497012,0.00001050914,0.0005585652],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0525646,"threshold_uncertainty_score":0.9994649,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00998712028710747,"score_gpt":0.2437942272246095,"score_spread":0.233807106937502,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}