{"id":"W2141605249","doi":"10.1139/v00-101","title":"CP/MAS NMR and X-ray crystallographic characterization of <i>trans</i>-PdX<sub>2</sub>(PPh<sub>2</sub>vinyl)<sub>2</sub> (X = Cl, I); UV and Et<sub>2</sub>O·BF<sub>3</sub> reaction studies, including the formation of [Pd(µ-Cl)(PPh<sub>2</sub>vinyl)<sub>2</sub>]<sub>2</sub>[BF<sub>4</sub>]<sub>2</sub>","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Phosphine; Nuclear magnetic resonance spectroscopy; NMR spectra database; Crystallography; Dissolution; Stereochemistry; Medicinal chemistry; Spectral line; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000689748,0.0002590315,0.0001593173,0.00009637829,0.0001566867,0.0002874476,0.0002523272,0.0001943371,0.002631481],"category_scores_gemma":[0.0001940027,0.0002124028,0.00008976892,0.0002072565,0.000241734,0.0002006889,0.0001237454,0.0004777366,0.0004266076],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003388415,"about_ca_system_score_gemma":0.0001804585,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008903714,"about_ca_topic_score_gemma":0.001000802,"domain_scores_codex":[0.9999266,0.000007978721,0.000004055743,0.00001527709,0.00003420022,0.00001189198],"domain_scores_gemma":[0.9999357,0.000008338913,0.00002067467,0.000006950632,0.00001498501,0.00001329987],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001171746,0.00001288611,0.0001632314,0.00005082562,0.000004856389,0.0000859348,0.0000404658,0.0002911984,0.9975338,0.0002036609,0.0002387665,0.001257242],"study_design_scores_gemma":[0.00001398114,0.0001309926,0.002956691,0.000003612355,0.000009548042,0.0002269443,0.00005757377,0.001000873,0.9899271,0.00006673454,0.005598703,0.000007353281],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9749376,0.000792842,0.009592395,0.0001921767,0.00003700064,0.00004950487,0.001779003,0.0001832986,0.01243628],"genre_scores_gemma":[0.9828781,0.0006745136,0.005537718,0.00008613379,0.000007663407,0.00003926754,0.002532599,0.0001412984,0.008102718],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002631481,"threshold_uncertainty_score":0.008803189,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01460687738152186,"score_gpt":0.2099983844866419,"score_spread":0.19539150710512,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}