{"id":"W2141721007","doi":"10.1039/c4cc00930d","title":"Slow relaxation in the first penta-aza Dy(<scp>iii</scp>) macrocyclic complex","year":2014,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor; Brock University","funders":"","keywords":"Relaxation (psychology); Chemistry; Crystallography; Stereochemistry; Medicinal chemistry; Psychology; Neuroscience","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009007777,0.0001702546,0.0002151517,0.00008231099,0.0004672131,0.0001808202,0.002972092,0.00009985449,0.0001300088],"category_scores_gemma":[0.001115116,0.0001457102,0.00007318245,0.0004337888,0.0004255788,0.0001961159,0.0006559757,0.0003416762,0.0004857648],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009195062,"about_ca_system_score_gemma":0.00002281825,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001748674,"about_ca_topic_score_gemma":0.000320974,"domain_scores_codex":[0.9982002,0.0003558197,0.0004964463,0.0002978139,0.0003415456,0.0003081762],"domain_scores_gemma":[0.9946257,0.002709544,0.0002236165,0.00226472,0.0001092864,0.0000671513],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000006620106,0.0005015266,0.001446518,0.00004763719,0.000007536848,6.647484e-7,0.003298603,0.00005203571,0.8526742,0.06192444,0.0775255,0.002514716],"study_design_scores_gemma":[0.001430982,0.0000570509,0.03498347,0.00007087959,0.00004653693,0.00003386429,0.001011627,0.02051223,0.1571952,0.02346311,0.7608843,0.0003106784],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9137378,0.0003131505,0.001945897,0.02086805,0.0001768595,0.0006618845,0.00003122507,0.0002380093,0.06202717],"genre_scores_gemma":[0.9912294,0.00004273197,0.006602342,0.00138965,0.00009861299,0.0002285605,0.0001648949,0.00001846839,0.0002253782],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.695479,"threshold_uncertainty_score":0.6243685,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0476955481422271,"score_gpt":0.2925883572391245,"score_spread":0.2448928090968974,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}