{"id":"W2141912851","doi":"10.1002/chem.201405555","title":"Functionalization of Hydride‐Terminated Photoluminescent Silicon Nanocrystals with Organolithium Reagents","year":2014,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Silicon Nanostructures and Photoluminescence","field":"Materials Science","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Hydrosilylation; Surface modification; Hydride; Electrophile; Nanocrystal; Reagent; Silicon; Materials science; Photoluminescence; Quenching (fluorescence); Cleavage (geology); Silanes; Nanotechnology; Photochemistry; Polymer chemistry; Chemical engineering; Chemistry; Fluorescence; Organic chemistry; Catalysis; Physical chemistry; Silane; Optoelectronics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006359119,0.0002273619,0.0002636833,0.00003895386,0.0001806631,0.0001146248,0.0004071959,0.00004524097,0.002219763],"category_scores_gemma":[0.0002000039,0.0001779063,0.00007242887,0.0002045054,0.0001830528,0.0001535183,0.00006985065,0.0001840892,0.00003370456],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004430371,"about_ca_system_score_gemma":0.00007806682,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000646848,"about_ca_topic_score_gemma":6.428745e-7,"domain_scores_codex":[0.9982114,0.0002096577,0.0005406811,0.0003163684,0.0004208485,0.0003009989],"domain_scores_gemma":[0.9984782,0.00003789545,0.0005674523,0.0003613337,0.0003417279,0.0002133554],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001264855,0.00005122902,0.001756429,0.00009878081,0.00001096622,0.0000466437,0.0001186707,0.00004637706,0.9962496,0.000003708773,0.001106907,0.0003841645],"study_design_scores_gemma":[0.0009978859,0.0001158432,0.004390746,0.0001949093,0.00003317207,0.00123097,0.00006153524,0.0004449909,0.98643,0.00001515346,0.005859776,0.0002250199],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969121,0.00004376955,0.000351023,0.00004099759,0.0002927032,0.00008806088,0.00002139419,0.00004650049,0.002203436],"genre_scores_gemma":[0.998507,0.00001315049,0.000157968,0.0001007026,0.0003209591,0.000001595856,0.00002823751,0.00004213063,0.0008283154],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009819641,"threshold_uncertainty_score":0.9986923,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006420093551539999,"score_gpt":0.1911561759183258,"score_spread":0.1847360823667858,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}