{"id":"W2141935913","doi":"10.1002/anie.200805512","title":"The Norbornene Shuttle: Multicomponent Domino Synthesis of Tetrasubstituted Helical Alkenes through Multiple CH Functionalization","year":2009,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":148,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Norbornene; Alkene; Surface modification; Domino; Catalysis; Norbornadiene; Chemistry; Dance; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001160883,0.000309703,0.0001715781,0.000217,0.0001626598,0.000344333,0.0004501403,0.0002089498,0.001606726],"category_scores_gemma":[0.0001140207,0.0001974947,0.0001741963,0.0001469064,0.0003094217,0.0006768439,0.0004278989,0.0004265515,0.0004144072],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002706603,"about_ca_system_score_gemma":0.0002771161,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003318372,"about_ca_topic_score_gemma":0.0008368056,"domain_scores_codex":[0.9999422,0.000004489869,0.000003386656,0.00001854016,0.00001217495,0.00001923884],"domain_scores_gemma":[0.9999561,0.00000801886,0.00001017843,0.000009428769,0.000004815629,0.00001157039],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001916832,0.000069755,0.0002627798,0.0001329552,0.00001623049,0.000322867,0.0001734516,0.001593891,0.9648645,0.01009411,0.0002707456,0.02200699],"study_design_scores_gemma":[0.00004820174,0.0005064685,0.00033515,0.00000955969,0.00001082945,0.0002316903,0.0000440946,0.00335004,0.9862759,0.001343897,0.007821728,0.0000224339],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9741089,0.0008544582,0.01598129,0.0001696839,0.00007537177,0.00005605381,0.0001527306,0.0002760376,0.008325544],"genre_scores_gemma":[0.9890882,0.0005835154,0.005059212,0.00003161822,0.00000581734,0.0000220267,0.00007267132,0.00002876094,0.005108227],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001606726,"threshold_uncertainty_score":0.005375028,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02466464049201028,"score_gpt":0.2821394751356297,"score_spread":0.2574748346436194,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}