{"id":"W2141961987","doi":"10.1039/b304176j","title":"Amidate complexes of titanium and zirconium: a new class of tunable precatalysts for the hydroamination of alkynesElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b304176j/","year":2003,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":129,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Zirconium; Titanium; Hydroamination; Chemistry; Chromatin structure remodeling (RSC) complex; Class (philosophy); Combinatorial chemistry; Catalysis; Computer science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003427508,0.0001930718,0.0003482875,0.000131121,0.0001718813,0.0000245675,0.0008466058,0.0001241834,0.0004626553],"category_scores_gemma":[0.0002491398,0.0001745274,0.000135417,0.0005577162,0.0003343063,0.0003849375,0.0002778935,0.0001936048,0.00001314535],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001352402,"about_ca_system_score_gemma":0.0001913425,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002642863,"about_ca_topic_score_gemma":0.00004015352,"domain_scores_codex":[0.9983885,0.00004743897,0.0008309114,0.0001904628,0.000305043,0.0002375951],"domain_scores_gemma":[0.9972935,0.0004717364,0.0005659628,0.001309363,0.0002727429,0.00008666774],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004883884,0.0006025593,0.0003614589,0.0002376891,0.0002966934,3.48415e-8,0.0007023223,0.000008077657,0.9841931,0.007994552,0.003884889,0.001669762],"study_design_scores_gemma":[0.001611117,0.00003430017,0.00002700502,0.00002903361,0.0002049107,0.000004619771,0.001374624,0.005190624,0.9541134,0.0001334853,0.03712633,0.0001505945],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.969619,0.008339141,0.002402497,0.0009949075,0.00004771965,0.001094412,0.001575857,0.00007265111,0.01585384],"genre_scores_gemma":[0.9928887,0.0003968962,0.002330205,0.00004054305,0.00001186424,0.0001173001,0.003767261,0.00001792146,0.0004292872],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03324144,"threshold_uncertainty_score":0.7117022,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02294577831596923,"score_gpt":0.2660658933209489,"score_spread":0.2431201150049797,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}