{"id":"W2141994105","doi":"10.1039/b814219j","title":"Electron induced dissociation in condensed-phase nitromethane I: desorption of ionic fragments","year":2009,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Nitromethane; Chemistry; Dissociation (chemistry); Desorption; Ion; Mass spectrometry; Molecule; Ionic bonding; Electron; Analytical Chemistry (journal); Electron ionization; Photochemistry; Physical chemistry; Ionization; Adsorption; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001264775,0.0003201343,0.0002040564,0.0001236664,0.0001263419,0.000136858,0.0002332937,0.0002636291,0.0007145954],"category_scores_gemma":[0.0002599122,0.0001173321,0.0001282211,0.0001052508,0.000242101,0.0002513391,0.000234103,0.0002486555,0.000134164],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001857085,"about_ca_system_score_gemma":0.0001128645,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004752199,"about_ca_topic_score_gemma":0.0007430369,"domain_scores_codex":[0.9999044,0.00000987853,0.000003651868,0.00002294495,0.00003926016,0.00001986544],"domain_scores_gemma":[0.9998447,0.00004599791,0.00004117682,0.00001021871,0.00003790142,0.00002009086],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003078483,0.000002862154,0.0004333479,0.00002061412,0.000001920032,0.00001702597,0.0000164639,0.00002489401,0.9990956,0.00001942356,0.000005009106,0.0003321545],"study_design_scores_gemma":[0.000003765108,0.00008317759,0.003818195,0.000002478698,0.00000264504,0.00008608909,0.0000222015,0.0004365226,0.9951752,0.00002102198,0.0003462654,0.000002348288],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974511,0.0004434561,0.001542395,0.00001748924,0.000004445916,0.000005725981,0.00006314761,0.00001557103,0.0004566086],"genre_scores_gemma":[0.9969934,0.0003125134,0.001740473,0.00002246779,0.000003009927,0.000009930167,0.0001515599,0.000008807479,0.000757877],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007145954,"threshold_uncertainty_score":0.002390563,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01415069944888652,"score_gpt":0.3048777566689181,"score_spread":0.2907270572200316,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}