{"id":"W2142237289","doi":"10.1039/b504926a","title":"Infrared spectra of homogeneous and heterogeneous proton-bound dimers in the gas phase","year":2005,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":81,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo; Memorial University of Newfoundland","funders":"","keywords":"Homogeneous; Gas phase; Infrared; Proton; Infrared spectroscopy; Spectral line; Phase (matter); Chemistry; Chemical physics; Materials science; Physical chemistry; Physics; Organic chemistry; Thermodynamics; Optics; Nuclear physics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00004557776,0.0003590571,0.0004301822,0.0000081177,0.00005582916,0.00004317541,0.000463071,0.0001566979,0.000121978],"category_scores_gemma":[0.00004144013,0.0002953661,0.000207387,0.0001908386,0.0003578974,0.00007204723,0.0000982286,0.0006246721,0.000003652578],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007465642,"about_ca_system_score_gemma":0.00004640551,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005930118,"about_ca_topic_score_gemma":3.110534e-7,"domain_scores_codex":[0.9983293,0.00001633787,0.0003296689,0.0004856338,0.0004037542,0.0004353508],"domain_scores_gemma":[0.9989942,0.0001061484,0.0001465397,0.0005803291,0.00003834653,0.0001344787],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001189887,0.0008101481,0.00002580696,0.0003328828,0.00004696767,0.00002520464,0.0005160206,0.0000983614,0.9953477,0.0001740556,0.00004144773,0.00246245],"study_design_scores_gemma":[0.001185396,0.00002556915,0.000001253117,0.00003442038,0.00004960517,0.00005046355,0.00004341997,0.002760489,0.9827509,0.01216864,0.0006255977,0.0003042291],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9865515,0.0001711119,0.00005015228,0.0001190588,0.000006664504,0.0001632956,0.00005382815,0.00004011668,0.01284433],"genre_scores_gemma":[0.998715,0.00001870207,0.0001821557,0.00008734302,0.0007623204,0.00006686083,0.00007090031,0.0000359031,0.00006085924],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01278347,"threshold_uncertainty_score":0.9999499,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007034968301623493,"score_gpt":0.2567436580608318,"score_spread":0.2497086897592083,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}