{"id":"W2142580097","doi":"10.1002/cplu.201300308","title":"Influence of Chromophore Length and Acceptor Groups on the Optical Properties of Rigidified Merocyanine Dyes","year":2013,"lang":"en","type":"article","venue":"ChemPlusChem","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; Compute Canada; Carl-Zeiss-Stiftung","keywords":"Solvatochromism; Merocyanine; Malononitrile; Chromophore; Substituent; Photochemistry; Moiety; Chemistry; Acceptor; Spectroscopy; Absorption spectroscopy; Isophorone; Photochromism; Molecule; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001947253,0.0003592972,0.0001807978,0.0001316396,0.00007615496,0.0002113896,0.0001693578,0.0001906711,0.001223983],"category_scores_gemma":[0.0003771155,0.0001140147,0.0001106635,0.0001598712,0.0001807532,0.0002474845,0.0001531467,0.0002727851,0.0001669717],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000146151,"about_ca_system_score_gemma":0.000102674,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000238343,"about_ca_topic_score_gemma":0.0004816015,"domain_scores_codex":[0.9998899,0.00002151223,0.00001117476,0.00002668727,0.0000271512,0.00002352463],"domain_scores_gemma":[0.9997298,0.0001026097,0.00006992443,0.00002627778,0.00002796589,0.00004333176],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002141855,0.00001568056,0.0001423253,0.0000422102,0.000003996208,0.00003013533,0.00001378843,0.0003357627,0.9977315,0.00005591105,0.00000766513,0.001406775],"study_design_scores_gemma":[0.00001233925,0.000426785,0.001574884,0.000004416134,0.00001681038,0.00004745755,0.00001112606,0.0008110853,0.9966803,0.00001517785,0.0003935328,0.000006208635],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986141,0.0002732641,0.000502845,0.00001050019,0.000003189983,0.000005558523,0.00004545888,0.00001443408,0.0005306115],"genre_scores_gemma":[0.9981899,0.0002857496,0.0009808117,0.00001169528,0.000002257111,0.00000896327,0.00007410449,0.00001248869,0.0004340667],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001223983,"threshold_uncertainty_score":0.004094601,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01684709925623749,"score_gpt":0.2078024873596103,"score_spread":0.1909553881033728,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}