{"id":"W2142594408","doi":"10.1039/c4fd00107a","title":"Rigid biimidazole ancillary ligands as an avenue to bright deep blue cationic iridium(<scp>iii</scp>) complexes","year":2014,"lang":"en","type":"article","venue":"Faraday Discussions","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Engineering and Physical Sciences Research Council","keywords":"Iridium; Microsecond; Cationic polymerization; Chemistry; Quantum yield; Photoluminescence; Ligand (biochemistry); Pyridine; Density functional theory; Yield (engineering); Excited state; Photochemistry; Kinetics; Crystallography; Catalysis; Computational chemistry; Materials science; Medicinal chemistry; Polymer chemistry; Fluorescence; Optoelectronics; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003844116,0.0003556637,0.0003783162,0.0002745701,0.0004684193,0.0001955384,0.0007337967,0.0001914245,0.00009700232],"category_scores_gemma":[0.0003940307,0.0002770751,0.0001180946,0.0006998946,0.00008397696,0.0002948023,0.000194063,0.0004579856,0.001572153],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002061292,"about_ca_system_score_gemma":0.0001017053,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008455099,"about_ca_topic_score_gemma":0.0002494995,"domain_scores_codex":[0.997532,0.00008531662,0.000429148,0.000517023,0.0005818224,0.0008546666],"domain_scores_gemma":[0.9978716,0.0002576947,0.00005262335,0.0010191,0.00009844876,0.0007004927],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000409057,0.001190232,0.007248021,0.0006648774,0.0006147259,0.0001253966,0.04445415,0.02885975,0.6759956,0.02130121,0.2047236,0.01478152],"study_design_scores_gemma":[0.0009476222,0.0001965825,0.01521319,0.0001715419,0.00006188834,0.00006083245,0.000944167,0.03711581,0.567521,0.0007344224,0.3764792,0.0005536832],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9865286,0.0002736566,0.004355795,0.0007800385,0.0006946823,0.0004300592,0.00006551969,0.0007381321,0.006133504],"genre_scores_gemma":[0.9959761,0.00004438078,0.0008290824,0.0002006789,0.0006715031,0.00007324945,0.000127873,0.0001346963,0.001942466],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1717557,"threshold_uncertainty_score":0.9999682,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008259359261421781,"score_gpt":0.2478408587228192,"score_spread":0.2395814994613974,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}