{"id":"W2142612756","doi":"10.1002/anie.200503255","title":"Highly Efficient Cross‐Dehydrogenative‐Coupling between Ethers and Active Methylene Compounds","year":2006,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":285,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Methylene; Simple (philosophy); Coupling (piping); Chemistry; Scheme (mathematics); Catalysis; Content (measure theory); Computer science; Combinatorial chemistry; Organic chemistry; Materials science; Philosophy; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000305924,0.0002328647,0.0002150355,0.0001388264,0.0001726655,0.0001273865,0.0001900765,0.0001799429,0.001033514],"category_scores_gemma":[0.0002075471,0.000250809,0.0001085228,0.0001669744,0.0001972486,0.0002359062,0.00009777232,0.0002347249,0.00002249228],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004187807,"about_ca_system_score_gemma":0.00005072218,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001621519,"about_ca_topic_score_gemma":0.000007823169,"domain_scores_codex":[0.998266,0.00001252941,0.0004075588,0.0004646405,0.0006295912,0.0002196423],"domain_scores_gemma":[0.9985935,0.0004786239,0.000264525,0.0001778373,0.0003988456,0.0000866318],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001968413,0.0002652078,0.0116299,0.0001051178,0.0004515857,0.00001296401,0.0003976735,0.01522365,0.958798,0.003117113,0.008361751,0.001440193],"study_design_scores_gemma":[0.0009768057,0.000008811734,0.00442739,0.00005269841,0.00005727607,0.00001506625,0.0001022739,0.00330662,0.9668232,0.001677398,0.02229268,0.000259777],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9215924,0.000147943,0.02042406,0.0007862272,0.0012517,0.0001121992,0.0006586618,0.0002171776,0.05480965],"genre_scores_gemma":[0.9892867,0.00001702978,0.0008794314,0.00008343615,0.004805441,0.00004271815,0.003268556,0.00003855063,0.001578123],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06769433,"threshold_uncertainty_score":0.9999944,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02100139712549051,"score_gpt":0.3025366911132765,"score_spread":0.281535293987786,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}