{"id":"W2142636122","doi":"10.1039/b702497e","title":"Rhodium(i)-catalyzed hydroaminomethylation of 2-isopropenylanilines as a novel route to 1,2,3,4-tetrahydroquinolines","year":2007,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Rhodium; Intramolecular force; Regioselectivity; Catalysis; Chemistry; Phosphine; Combinatorial chemistry; Ionic bonding; Organic chemistry; Medicinal chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001818748,0.000379484,0.0002650248,0.0001486657,0.0001094446,0.0001670932,0.0005679642,0.000282298,0.001159485],"category_scores_gemma":[0.0001298233,0.0002065774,0.0002452806,0.00006097442,0.0001865195,0.0003049547,0.0002383716,0.0004211513,0.0006685915],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000184095,"about_ca_system_score_gemma":0.0001703819,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003027675,"about_ca_topic_score_gemma":0.0005767544,"domain_scores_codex":[0.9998842,0.00002043896,0.000009849451,0.00003133782,0.00003123925,0.0000228613],"domain_scores_gemma":[0.9999353,0.000009554317,0.00002006032,0.00001327035,0.000008658022,0.00001311617],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002488637,0.00001096924,0.00002784168,0.00005203376,0.000003341048,0.00009928901,0.00001932588,0.0001304803,0.9970673,0.0002087234,0.00005010213,0.002305809],"study_design_scores_gemma":[0.00001914869,0.0001585965,0.0002690079,0.000003169107,0.000009966433,0.0003722842,0.000006941493,0.0005938758,0.9947695,0.00005143716,0.003737642,0.000008566248],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9402652,0.00389248,0.04340754,0.0002342598,0.00009838268,0.0001356745,0.0003194275,0.0007077645,0.01093914],"genre_scores_gemma":[0.9715244,0.001661023,0.02122965,0.00006508351,0.00003159267,0.00005971214,0.0003124306,0.00008435968,0.005031656],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001159485,"threshold_uncertainty_score":0.003878891,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0637427812366398,"score_gpt":0.3506581022921394,"score_spread":0.2869153210554996,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}