{"id":"W2142860173","doi":"10.1002/chem.201300376","title":"Unusual Structure, Fluxionality, and Reaction Mechanism of Carbonyl Hydrosilylation by Silyl Hydride Complex [(ArN)Mo(H)(SiH<sub>2</sub>Ph)(PMe<sub>3</sub>)<sub>3</sub>]","year":2013,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"American Chemical Society Petroleum Research Fund; Durham University; Royal Society","keywords":"Hydrosilylation; Chemistry; Silylation; Intramolecular force; Phosphine; Hydride; Ligand (biochemistry); Silane; Medicinal chemistry; Borohydride; Silanes; Stereochemistry; Catalysis; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005263325,0.0001718759,0.000104565,0.00007299425,0.0001141761,0.0001837588,0.0002533754,0.0002617844,0.001137192],"category_scores_gemma":[0.00007289874,0.0001270791,0.0001137088,0.00006869865,0.0002212157,0.0002503856,0.0001508038,0.0002949313,0.0001883083],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002166399,"about_ca_system_score_gemma":0.00008702086,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003827453,"about_ca_topic_score_gemma":0.0004672637,"domain_scores_codex":[0.9999696,0.000002899006,0.000001539568,0.000008953377,0.000007007776,0.00001000229],"domain_scores_gemma":[0.99997,0.000004007255,0.00001175996,0.000003922065,0.000003640032,0.000006604693],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001472243,0.000009413519,0.000261633,0.00004658647,0.00000793153,0.00009209319,0.00004560383,0.000187259,0.9972351,0.0006718826,0.00006181258,0.001233568],"study_design_scores_gemma":[0.00001330833,0.00007792911,0.001471293,0.000001974076,0.000006681697,0.0001577116,0.00001814684,0.000904926,0.995944,0.0001465618,0.001251298,0.00000620393],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964805,0.0002852122,0.001411148,0.00004701006,0.000005820314,0.00000975318,0.00007835693,0.00005316427,0.001629088],"genre_scores_gemma":[0.9985185,0.0001129759,0.0005319274,0.00001546195,0.000002345765,0.000006980797,0.00008637814,0.00001198699,0.0007134718],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001137192,"threshold_uncertainty_score":0.003804326,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009849314240643664,"score_gpt":0.1998371475005743,"score_spread":0.1899878332599306,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}