{"id":"W2142910570","doi":"10.1002/jps.20601","title":"Dynamic Heat Capacity and Relaxation Time of Ultraviscous Melt and Glassy Acetaminophen","year":2006,"lang":"en","type":"article","venue":"Journal of Pharmaceutical Sciences","topic":"Material Dynamics and Properties","field":"Materials Science","cited_by":32,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University","funders":"Centre National de la Recherche Scientifique; Pfizer","keywords":"Supercooling; Heat capacity; Thermodynamics; Relaxation (psychology); Glass transition; Nucleation; Atmospheric temperature range; Vitrification; Dielectric; Materials science; Configuration entropy; Chemistry; Analytical Chemistry (journal); Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001453758,0.0001565472,0.0001418066,0.0002466238,0.0001752327,0.0001745229,0.0002151657,0.0002200792,0.002120142],"category_scores_gemma":[0.0004030639,0.0001111791,0.000167592,0.0001852388,0.0002818207,0.0003042331,0.00011761,0.0003883649,0.0001912082],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002193084,"about_ca_system_score_gemma":0.0001863213,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002174641,"about_ca_topic_score_gemma":0.001121148,"domain_scores_codex":[0.999904,0.00001090101,0.000004816256,0.00002076035,0.00002706793,0.00003243409],"domain_scores_gemma":[0.9997249,0.0001299725,0.00006496615,0.00001703438,0.00003499571,0.0000280201],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001097489,0.00004676661,0.001977868,0.00003853467,0.00001529131,0.0001116927,0.0001227642,0.0008723936,0.9913664,0.0001744286,0.00007163337,0.004104669],"study_design_scores_gemma":[0.00001012147,0.0004515797,0.01807717,0.000005356671,0.0000195571,0.00007640522,0.00009476201,0.01077205,0.9699705,0.00005751056,0.0004530502,0.00001190384],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987287,0.0003093626,0.0003986385,0.00001849958,0.000006780545,0.000002486614,0.00009130798,0.000009581399,0.000434698],"genre_scores_gemma":[0.9989496,0.000108179,0.0001640537,0.000006018251,0.000004217381,0.000003329983,0.0001251679,0.000006223922,0.0006333265],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002174641,"threshold_uncertainty_score":0.007092595,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02140120365030531,"score_gpt":0.2834009348415065,"score_spread":0.2619997311912012,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}