{"id":"W2143004620","doi":"10.1039/c4sc01317d","title":"Enantioselective construction of C-chiral allylic sulfilimines via the iridium-catalyzed allylic amination with S,S-diphenylsulfilimine: asymmetric synthesis of primary allylic amines","year":2014,"lang":"en","type":"article","venue":"Chemical Science","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada; Queen's University; University of Liverpool; Royal Society","keywords":"Allylic rearrangement; Amination; Enantioselective synthesis; Iridium; Catalysis; Chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002569959,0.0004590041,0.0002203866,0.0001869233,0.0001372239,0.0002479845,0.0004736195,0.0002677987,0.001344408],"category_scores_gemma":[0.0001786712,0.0001622157,0.0002239596,0.0001499101,0.0002432002,0.0002688335,0.0002921411,0.0004987189,0.0006220337],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000361121,"about_ca_system_score_gemma":0.0004114785,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002923721,"about_ca_topic_score_gemma":0.0008808463,"domain_scores_codex":[0.9998543,0.0000221149,0.00001492156,0.0000294697,0.00004103393,0.0000381566],"domain_scores_gemma":[0.9999141,0.0000101781,0.00002749517,0.00001426722,0.00001248044,0.00002149661],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000651997,0.00003367693,0.00009427256,0.00005881663,0.000006654784,0.0001895567,0.00003670331,0.0001894985,0.9934651,0.001183829,0.0001138438,0.004562825],"study_design_scores_gemma":[0.00001303696,0.000124444,0.0002455092,0.000002027179,0.000005558273,0.0001700584,0.000006370356,0.0004440995,0.9967063,0.00007492714,0.002203638,0.000003986276],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9453448,0.001173674,0.03173946,0.0002454669,0.000101331,0.0001524997,0.0004615322,0.0004259952,0.02035518],"genre_scores_gemma":[0.9856508,0.0006057561,0.01048102,0.00003622474,0.00001596463,0.00003533147,0.0002222747,0.00003405671,0.002918577],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001344408,"threshold_uncertainty_score":0.004497528,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006772231007965489,"score_gpt":0.2028617335694725,"score_spread":0.1960895025615071,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}