{"id":"W2143053035","doi":"10.1021/ic700573j","title":"Transition Metal-Catalyzed Dissociation of Phosphine−Gallane Adducts:  Isolation of Mechanistic Model Complexes and Heterogeneous Catalyst Poisoning Studies","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Phosphine; Catalysis; Cyclooctadiene; Adduct; Medicinal chemistry; Dissociation (chemistry); Bond cleavage; Photochemistry; Polymer chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004852764,0.0001486964,0.0003874151,0.00002585171,0.00007155315,0.00001419271,0.0001021234,0.00009212145,0.0001092507],"category_scores_gemma":[0.0001141247,0.000145395,0.00004429164,0.00008884227,0.00008697047,0.0001115559,0.00004976804,0.00004038032,0.000003408989],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006894492,"about_ca_system_score_gemma":0.00003179448,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007718113,"about_ca_topic_score_gemma":0.00002205246,"domain_scores_codex":[0.9988434,0.00001757332,0.0005141405,0.0002334259,0.0002149011,0.0001765892],"domain_scores_gemma":[0.9991913,0.00006692262,0.000357512,0.0001806088,0.0001545115,0.00004916427],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005245922,0.00004139513,0.00001095708,0.0003571298,0.00004946113,0.000003769685,0.001691227,0.0002171304,0.997515,0.00002686781,0.000004151618,0.00003051189],"study_design_scores_gemma":[0.0003158123,0.00001824614,0.00001584332,0.00005108345,0.0001211919,0.00002952701,0.0003831147,0.0007728471,0.9975983,0.0005618777,0.000001492873,0.0001306547],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937369,0.0008035997,0.005066971,0.0000193553,0.00006655179,0.0001075637,0.0001393528,0.00003804887,0.00002171638],"genre_scores_gemma":[0.9988175,0.00005240394,0.0009205596,0.000009843961,0.00004679704,0.000003507538,0.0001109427,0.00001632346,0.00002210348],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005080678,"threshold_uncertainty_score":0.5929037,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01739299943715754,"score_gpt":0.262078397046929,"score_spread":0.2446853976097715,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}