{"id":"W2143455876","doi":"10.1139/v01-040","title":"Synthesis of sulfated mono- and ditertiary phosphines, complex chemistry and catalysis","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Hungarian Science Foundation; National Science Foundation","keywords":"Hydroformylation; Chemistry; Rhodium; Styrene; Catalysis; Nucleophile; Amphiphile; Organic chemistry; Medicinal chemistry; Triphenylphosphine; Polymer chemistry; Copolymer","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001714172,0.0002051885,0.0004458448,0.0000781928,0.00009451419,0.0000465115,0.0002751633,0.0001849217,0.002627243],"category_scores_gemma":[0.0003940866,0.0002058197,0.0001350182,0.0003784244,0.0002316213,0.0001127195,0.00002826404,0.0002281764,0.000001303444],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001216609,"about_ca_system_score_gemma":0.0003751107,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001190793,"about_ca_topic_score_gemma":0.0002276137,"domain_scores_codex":[0.9987319,0.000007548002,0.0005697539,0.0002046986,0.0002224114,0.0002636832],"domain_scores_gemma":[0.9981661,0.0001084575,0.0004372042,0.0002640578,0.0002302234,0.0007939495],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000615703,0.00007514288,0.07293545,0.0007018179,0.0007518573,0.0004821384,0.0003826467,0.0000272204,0.8899357,0.000002271754,0.002870365,0.03177383],"study_design_scores_gemma":[0.0005341098,0.000004502056,0.002213545,0.0001131881,0.0002518828,0.001039882,0.0006477784,0.0003673113,0.9848201,0.00003498027,0.009696301,0.0002764592],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9864062,0.002307021,0.00002058553,0.0004111083,0.00001307861,0.00001453695,0.00007714298,0.000008312082,0.01074203],"genre_scores_gemma":[0.9984579,0.0003713777,0.00008288692,0.00004862042,0.0001078625,0.000002085184,0.0000486511,0.00002219941,0.0008583856],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09488438,"threshold_uncertainty_score":0.9982845,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008183091158820245,"score_gpt":0.1964404018998853,"score_spread":0.188257310741065,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}