{"id":"W2144145480","doi":"10.3998/ark.5550190.0011.715","title":"Tri-ionizable calix[4]arene ligands: synthesis and lanthanide ion complexation","year":2010,"lang":"en","type":"article","venue":"ARKIVOC","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Basic Energy Sciences; U.S. Department of Energy","keywords":"Chemistry; Potentiometric titration; Lanthanide; Titration; Ligand (biochemistry); Calixarene; Ion; Sulfonyl; Chelation; Inorganic chemistry; Polymer chemistry; Medicinal chemistry; Stereochemistry; Organic chemistry; Molecule; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003509659,0.0001273742,0.0001927599,0.00006464508,0.0002228172,0.0001225412,0.0001305516,0.00006676744,0.001350305],"category_scores_gemma":[0.00009673242,0.0001042884,0.00003841693,0.0001109319,0.00009347522,0.0002551267,0.00003795305,0.00009862844,0.0002822952],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000007143334,"about_ca_system_score_gemma":0.00002148564,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003988839,"about_ca_topic_score_gemma":0.0004632667,"domain_scores_codex":[0.9990743,0.00004326008,0.000203698,0.0002705511,0.0001886475,0.0002195315],"domain_scores_gemma":[0.9993763,0.0001750711,0.00007216747,0.0002209705,0.00005836431,0.0000971338],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002623123,0.00003433839,0.0006056764,0.00002115016,0.000004987334,0.000006526263,0.00009529058,0.000003052906,0.9937561,0.004377781,0.0004091178,0.0006598126],"study_design_scores_gemma":[0.0002742181,0.00003749632,0.005497771,0.00002408662,0.00003090173,0.00004022624,0.00005081633,0.0002589085,0.985267,0.004478075,0.003869312,0.0001711784],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960818,0.00006673646,0.0008269159,0.0004109104,0.0004579666,0.0001169784,0.00005324533,0.0001179231,0.001867494],"genre_scores_gemma":[0.9976251,0.000036739,0.001767328,0.0001742545,0.0001934498,0.00001861102,0.00002041183,0.00001429015,0.0001497964],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008489025,"threshold_uncertainty_score":0.9995626,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01400058656986285,"score_gpt":0.2270797426509024,"score_spread":0.2130791560810396,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}