{"id":"W2144332013","doi":"10.1002/poc.1423","title":"Supramolecular encapsulation of 1,3‐bis(1‐adamantyl)imidazolium chloride by β‐cyclodextrins: towards inhibition of C(2)‐H/D exchange","year":2008,"lang":"en","type":"article","venue":"Journal of Physical Organic Chemistry","topic":"Chemical Synthesis and Characterization","field":"Environmental Science","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Supramolecular chemistry; Cyclodextrin; Hydrogen–deuterium exchange; Proton NMR; Hydrogen bond; Chloride; Carbene; Medicinal chemistry; Organic chemistry; Polymer chemistry; Combinatorial chemistry; Catalysis; Molecule; Hydrogen","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001113426,0.0001400765,0.0003389374,0.0000138874,0.00003334437,0.000005395378,0.0001675731,0.00009320529,0.00114068],"category_scores_gemma":[0.0001145774,0.0001240205,0.0001831625,0.0002272352,0.000150156,0.0002050465,0.00008452526,0.0001657437,0.000006168512],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001330737,"about_ca_system_score_gemma":0.00003444984,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002043832,"about_ca_topic_score_gemma":2.582468e-7,"domain_scores_codex":[0.9985941,0.00001863175,0.0005163611,0.0001517253,0.0005727041,0.0001464724],"domain_scores_gemma":[0.9989699,0.00004023002,0.0006682404,0.000158871,0.00005613513,0.0001066987],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004795721,0.0003970525,0.0004732978,0.00005827036,0.00001762034,0.000005591338,0.0002034322,0.00001822692,0.9976003,0.000002346843,0.0003506735,0.0008252885],"study_design_scores_gemma":[0.0004039569,0.0000563642,0.005085675,0.00005163666,0.00003636811,0.00003166437,0.00002552204,0.0001190521,0.993432,0.00007551146,0.0005662514,0.0001160264],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982995,0.00004109331,0.0004064213,0.000129848,0.00002640083,0.00004941682,0.00001499195,0.000006277394,0.001026036],"genre_scores_gemma":[0.9995,0.00008476451,0.00006110661,0.00002071672,0.0001950559,0.000001092705,0.00001583121,0.00001618032,0.0001052937],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004612377,"threshold_uncertainty_score":0.9997724,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004978965167725312,"score_gpt":0.1863975709413458,"score_spread":0.1814186057736205,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}