{"id":"W2144431385","doi":"10.1002/chem.200903174","title":"The Effect of Incorporating Fréchet Dendrons into Rotaxanes and Molecular Shuttles Containing the 1,2‐Bis(pyridinium)ethane⊂[24]Crown‐8 Templating Motif","year":2010,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Rotaxane; Dendrimer; Pyridinium; Supramolecular chemistry; Chemistry; Molecule; Stereochemistry; Solubility; Crown ether; Crystallography; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002380385,0.0004747882,0.0001941328,0.0001057869,0.0001084347,0.000298038,0.0002073897,0.0003150264,0.0007130977],"category_scores_gemma":[0.0003709593,0.0002153712,0.0001856728,0.0001352551,0.0002988948,0.0004615275,0.0001955419,0.000375026,0.000156237],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001925825,"about_ca_system_score_gemma":0.0001471141,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003570346,"about_ca_topic_score_gemma":0.0006499403,"domain_scores_codex":[0.9998726,0.00003162512,0.00001357,0.00002511569,0.00001943307,0.00003768148],"domain_scores_gemma":[0.9997132,0.00009199965,0.00008347707,0.00002087548,0.00002917833,0.0000612626],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004500929,0.00007078622,0.000153176,0.00007763803,0.00001402806,0.00005371724,0.00003619243,0.0003673853,0.9970928,0.0001252795,0.000020657,0.00153818],"study_design_scores_gemma":[0.00002485089,0.000762745,0.0007679007,0.000003799282,0.00001589371,0.00003640223,0.000009221542,0.0005481955,0.9973553,0.000017972,0.0004502305,0.000007428871],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9989856,0.0001592118,0.0003472979,0.00001161686,0.000008461215,0.00001347148,0.00002808268,0.00002638612,0.0004199002],"genre_scores_gemma":[0.9977376,0.0002525731,0.001322774,0.00002284792,0.000005632673,0.00001486553,0.00006788721,0.00001322568,0.0005626244],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007130977,"threshold_uncertainty_score":0.002385616,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006792432788242183,"score_gpt":0.2172661491222616,"score_spread":0.2104737163340194,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}