{"id":"W2144431385","doi":"10.1002/chem.200903174","title":"The Effect of Incorporating Fréchet Dendrons into Rotaxanes and Molecular Shuttles Containing the 1,2‐Bis(pyridinium)ethane⊂[24]Crown‐8 Templating Motif","year":2010,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Rotaxane; Dendrimer; Pyridinium; Supramolecular chemistry; Chemistry; Molecule; Stereochemistry; Solubility; Crown ether; Crystallography; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.002433186,0.0004559059,0.0003851809,0.00001978899,0.001066359,0.0005343073,0.001214088,0.0001264906,0.0001856408],"category_scores_gemma":[0.001601487,0.0002969844,0.0002633588,0.0001485465,0.0006246513,0.0001219774,0.0003216583,0.002009613,0.000004311056],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002187478,"about_ca_system_score_gemma":0.00008833361,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007495976,"about_ca_topic_score_gemma":0.000002047606,"domain_scores_codex":[0.9974649,0.0003435511,0.0007613075,0.0004159214,0.0005276123,0.0004867274],"domain_scores_gemma":[0.9971236,0.0009563467,0.000813848,0.000748228,0.0001254765,0.0002325168],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001006837,0.00002085669,0.003039163,0.0002549944,0.0001201544,0.0004481739,0.0005317081,0.00002308413,0.9907796,0.0000268736,0.0001624513,0.00449223],"study_design_scores_gemma":[0.001010072,0.0000852197,0.00009303127,0.0002264984,0.0001270826,0.0043104,0.002566922,0.0005254769,0.9872395,0.0001346016,0.003321061,0.0003601023],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9824252,0.0007973813,0.0001564695,0.0002382555,0.0001213339,0.0000747303,0.000009358241,0.00005538691,0.01612195],"genre_scores_gemma":[0.9983951,0.00002113309,0.0006805109,0.00004590772,0.0006212656,0.00001156695,0.00002105353,0.00007325476,0.0001302382],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01599171,"threshold_uncertainty_score":0.9999482,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006792432788242183,"score_gpt":0.2172661491222616,"score_spread":0.2104737163340194,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}