{"id":"W2144627261","doi":"10.1002/chem.200400641","title":"Lewis Adducts of the Side‐On End‐On Dinitrogen‐Bridged Complex [{(NPN)Ta}<sub>2</sub>(μ‐H)<sub>2</sub>(μ‐η<sup>1</sup>:η<sup>2</sup>‐N<sub>2</sub>)] with AlMe<sub>3</sub>, GaMe<sub>3</sub>, and B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>: Synthesis, Structure, and Spectroscopic Properties","year":2004,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Deutsche Forschungsgemeinschaft","keywords":"Adduct; Chemistry; Lewis acids and bases; Bond length; Crystallography; Force constant; Nuclear magnetic resonance spectroscopy; Stereochemistry; Molecule; Crystal structure","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.003228806,0.007518652,0.006580589,0.001587204,0.004128119,0.003465801,0.005665401,0.002317239,0.0003485343],"category_scores_gemma":[0.002764752,0.006893578,0.002763505,0.003570463,0.004413525,0.00253645,0.002750478,0.008266342,0.0005663424],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002931883,"about_ca_system_score_gemma":0.002725326,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002034325,"about_ca_topic_score_gemma":0.00005531867,"domain_scores_codex":[0.9700258,0.002344985,0.007760933,0.007144473,0.006143661,0.006580169],"domain_scores_gemma":[0.9788113,0.001725752,0.006529656,0.006224265,0.002473701,0.004235313],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002746873,0.002566077,0.001616958,0.002653665,0.003385566,0.001514133,0.002377088,0.001507772,0.9568377,0.00006118308,0.002098682,0.02263431],"study_design_scores_gemma":[0.009949162,0.00114825,0.008846101,0.005302825,0.002585986,0.006798826,0.002042926,0.001356494,0.9535506,0.0003330471,0.001097492,0.006988265],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9870576,0.002725815,0.000287991,0.001436741,0.0009643572,0.002519241,0.002326563,0.001308562,0.00137317],"genre_scores_gemma":[0.980983,0.007953268,0.0002112552,0.001434791,0.005325262,0.0003223654,0.001203252,0.002512789,0.0000539881],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01564604,"threshold_uncertainty_score":0.9997144,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01604052753715817,"score_gpt":0.1916168477129472,"score_spread":0.175576320175789,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}