{"id":"W2144759551","doi":"10.1002/chin.200552263","title":"Application of Phosphonium Salts as Catalysts","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Phosphonium; Catalysis; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002698723,0.0004881248,0.0003179204,0.0003174888,0.0002104189,0.000686664,0.0004812259,0.0005354765,0.002868533],"category_scores_gemma":[0.0004307406,0.0002729789,0.0002151721,0.0002215456,0.0002060597,0.0005734955,0.0007563561,0.000625691,0.001572164],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002712205,"about_ca_system_score_gemma":0.0002414357,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003806443,"about_ca_topic_score_gemma":0.0004767501,"domain_scores_codex":[0.9998003,0.00003446771,0.00002472669,0.00005326331,0.00005788529,0.00002948579],"domain_scores_gemma":[0.9999282,0.0000180567,0.00000852243,0.00001881093,0.00001592107,0.0000104983],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002674496,0.00004976393,0.0001675218,0.0004758603,0.00002735303,0.0002053313,0.00005530388,0.000597849,0.9768724,0.002151063,0.0006680391,0.01846198],"study_design_scores_gemma":[0.00001798268,0.0001144738,0.00008405976,0.00001184744,0.00001294206,0.00009554431,0.0000129601,0.0005596909,0.990845,0.0001597112,0.008081713,0.000004082955],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8033498,0.02518257,0.04000799,0.001696191,0.001464163,0.0004512272,0.0007808235,0.0009544663,0.1261128],"genre_scores_gemma":[0.9688139,0.00744745,0.01056751,0.0001277913,0.00007569742,0.0000591003,0.0002948959,0.0001228012,0.01249085],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002868533,"threshold_uncertainty_score":0.009596229,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004730781048249321,"score_gpt":0.2128890351054542,"score_spread":0.2081582540572049,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}