{"id":"W2144846825","doi":"10.1002/chem.200390020","title":"Chemistry of Phosphine–Borane Adducts at Platinum Centers: Synthesis and Reactivity of Pt<sup>II</sup> Complexes with Phosphinoborane Ligands","year":2002,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Phosphine; Hydride; Ligand (biochemistry); Borane; Adduct; Medicinal chemistry; Reactivity (psychology); Oxidative addition; Stereochemistry; Nuclear magnetic resonance spectroscopy; Coordination complex; Metal; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004221978,0.0004381451,0.0006903561,0.00005489507,0.0002810056,0.00005434783,0.0005083296,0.000111227,0.005640935],"category_scores_gemma":[0.0003450676,0.0003891559,0.000220608,0.0004091001,0.0003977574,0.0001879991,0.0002333079,0.0005521639,0.00001209373],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001238347,"about_ca_system_score_gemma":0.00004062141,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006883002,"about_ca_topic_score_gemma":2.956889e-7,"domain_scores_codex":[0.997579,0.00003513237,0.0008282303,0.0004800993,0.0006708257,0.0004067155],"domain_scores_gemma":[0.9975603,0.0001671295,0.001005543,0.0005933882,0.0002815037,0.0003920886],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002497827,0.0004814704,0.002020828,0.0007517879,0.0004154635,0.0002720691,0.0008445361,0.0001046375,0.9876596,6.955859e-7,0.001340978,0.005858137],"study_design_scores_gemma":[0.001731846,0.00003794154,0.000170686,0.000387952,0.0002461293,0.001198437,0.0007000155,0.001985551,0.9901801,0.000002129132,0.002967847,0.0003914015],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9714679,0.001226279,0.00002358882,0.0001368172,0.00001349998,0.00003815713,0.0001840191,0.00005146445,0.02685829],"genre_scores_gemma":[0.9958702,0.0004611909,0.0002123855,0.00001822754,0.0002067868,0.000002627038,0.00005358649,0.00007711921,0.0030979],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02440229,"threshold_uncertainty_score":0.9998561,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0126647684291763,"score_gpt":0.1916281733856008,"score_spread":0.1789634049564245,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}